We isolated fulvic acids from two antarctic coastal ponds by means of preparative scale column chromatography with XAD‐8 resin. Both ponds are on Ross Island. Pony Lake at Cape Royds has abundant phytoplankton populations, and Feather Pond at Cape Bird has a luxuriant benthic algal mat. Neither site has higher plants in the watershed. The dissolved organic carbon (DOC) concentration in Pony Lake was very high, but the percentage of DOC accounted for by fulvic acid was low, as has been observed for other lakes with algal‐derived DOC sources. Fulvic acid from Pony Lake was more enriched in nitrogen than fulvic acid from Feather Pond, with a C: N atomic ratio of 13 in Pony Lake and a C: N ratio of 24 in Feather Pond. The [13C]NMR spectra for the coastal pond samples showed that the content of sp2‐hybridized carbon atoms (aromatic or olefinic) was only 16.5% of the total spectral area for Pony Lake and only 20.1% for Feather Pond.
The diatom Didymosphenia geminata is a single‐celled alga found in lakes, streams, and rivers. Nuisance blooms of D geminata affect the diversity, abundance, and productivity of other aquatic organisms. Because D geminata can be transported by humans on waders and other gear, accurate spatial prediction of habitat suitability is urgently needed for early detection and rapid response, as well as for evaluation of monitoring and control programs. We compared four modeling methods to predict D geminata's habitat distribution; two methods use presence–absence data (logistic regression and classification and regression tree [CART]), and two involve presence data (maximum entropy model [Maxent] and genetic algorithm for rule‐set production [GARP]). Using these methods, we evaluated spatially explicit, bioclimatic and environmental variables as predictors of diatom distribution. The Maxent model provided the most accurate predictions, followed by logistic regression, CART, and GARP. The most suitable habitats were predicted to occur in the western US, in relatively cool sites, and at high elevations with a high base‐flow index. The results provide insights into the factors that affect the distribution of D geminata and a spatial basis for the prediction of nuisance blooms.
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