A comparative study has been made of two species of planktonic foraminifera, G. tumida and G. sacculifer, in a depth transect on the Ontong Java Plateau, western equatorial Pacific. G. tumida tests from core‐top sediments showed decreasing Mg/Ca (2.65–1.25 mmol/mol) and Sr/Ca (1.50–1.16 mmol/mol) ratios with increasing water depth (1600–4400 m), while no such variation was found in G. sacculifer tests in excess of 355 µm (average Mg/Ca, 3.6 mmol/mol, Sr/Ca, 1.4 mmol/mol). Artificial dissolution of G. tumida tests led to a decrease in both Mg/Ca and Sr/Ca, but in G. sacculifer, there was no significant change in the ratios. Analyses by electron microprobe revealed that Mg/Ca of the inner (chamber) calcite in G. tumida tests was much higher than that of the calcite crust (keel), whereas Sr/Ca was only slightly elevated. There were no consistent spatial differences in either Mg/Ca or Sr/Ca for G. sacculifer tests. Dissolution in the oceans gives rise to the removal of the chamber calcite in G. tumida (about 30% of the total calcite), leaving the keel calcite. Although G. tumida is thought of as a dissolution‐resistant form, the majority of Mg/Ca and Sr/Ca depletion (and chamber loss) occurs above the lysocline. It is also possible that much of the Mg‐enriched gametogenic calcite has been lost by dissolution from G. sacculifer above 1600 m. Mg content has a significant effect on the dissolution susceptibility of planktonic foraminifera. Calculations show that the saturation horizon for Mg‐rich parts of tests may be elevated by several hundred meters compared with normal calcite.
Blue phases (BPs), a distinct class of liquid crystals (LCs) with 3D periodic ordering of double twist cylinders involving orthogonal helical director twists, have been theoretically studied as potential templates for tunable colloidal crystals. Here, we report the spontaneous formation of thermally reversible, cubic crystal nanoparticle (NP) assemblies in BPs. Gold NPs, functionalized to be highly miscible in cyanobiphenyl-based LCs, were dispersed in BP mixtures and characterized by polarized optical microscopy and synchrotron small-angle X-ray scattering (SAXS). The NPs assemble by selectively migrating to periodic strong trapping sites in the BP disclination lines. The NP lattice, remarkably robust given the small particle size (4.5 nm diameter), is commensurate with that of the BP matrix. At the BP I to BP II phase transition, the NP lattice reversibly switches between two different cubic structures. The simultaneous presence of two different symmetries in a single material presents an interesting opportunity to develop novel dynamic optical materials.
The term patient-centered communication (PCC) has been used to describe a group of communication strategies and behaviors that promote mutuality, shared understandings, and shared decision making in health care encounters. There is evidence to suggest that advanced practice nurse and patients use these strategies to co-produce highly individualized clinical discourse. Although the communication behaviors associated with PCC have been studied separately, their impact as an integrated communications strategy has not been studied. Suggestions for developing PCC as a mid-range theory of health care communication encompassing other more specific communication concepts are offered.
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