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Lithological heterogeneity is a widely accepted feature of the Earth's mantle, with recycled crustal material accounting for a significant part of heterogeneity in ocean island basalt (OIB) geochemistry. Fe isotopes have been used to link geochemical heterogeneity in OIB sources to distinct mantle lithologies due to their mineral-specific equilibrium fractionation effects, or their composition, such as incorporation of kinetically-fractionated core liquids entrained from the core-mantle boundary.Here we present Fe isotope data for Samoan shield, and Azores volcanoes, together with a combined phase-equilibria and equilibrium mineral-melt isotope fractionation model. These OIB lavas allow us to study the roles of core-derived and recycled mantle components in

Long-lived, widespread intraplate volcanism without age progression is one of the most controversial features of plate tectonics. Previously proposed edge-driven convection, asthenospheric shear, and lithospheric detachment fail to explain the ~5000-km-wide intraplate volcanic province from eastern Australia to Zealandia. We model the subducted slab volume over 100 million years and find that slab flux drives volcanic eruption frequency, indicating stimulation of an enriched mantle transition zone reservoir. Volcanic isotope geochemistry allows us to distinguish a high-μ (HIMU) reservoir [>1 billion years (Ga) old] in the slab-poor south, from a northern EM1/EM2 reservoir, reflecting a more recent voluminous influx of oceanic lithosphere into the mantle transition zone. We provide a unified theory linking plate boundary and slab volume reconstructions to upper mantle reservoirs and intraplate volcano geochemistry.

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