By tuning the extent of submergence of the rose petal structures with silicone oil, we could alter the adhesion characteristics of the surface on demand, while retaining its slippery characteristics for a wide range of the pertinent parameters.

No abstract

Electrowetting on dielectric (EWOD) on unidirectional microstructured surfaces has recently evoked significant interest as they can modulate the effect of electrowetting, and can thus find applications in directional wetting in microfluidic systems. However, the dependency of such EW phenomenon on their initial state of wetting and anisotropy is far from being well understood. The current study addresses the initial wetting states and their implication on the anisotropic electrowetting using a wrinkled EWOD platform. Herein we demonstrate a facile stampless and maskless structure generation technique to fabricate wrinkles of varying topography. Further, we have demonstrated alteration in the interfacial wetting conditions by modulating the wrinkle topography, and its effect on the droplet behavior during electrowetting. The capillary wicking-assisted electrowetting on these wrinkled surfaces is in specific direction dictated by the ordered wrinkles and prompts enhanced spreading of the droplet. We also demonstrate that while the enhancement of unidirectional electrowetting is stronger in conformal wetting state surfaces, composite wetting state surfaces depict a reversal in anisotropy.

Generating controlled vortices in a sessile surface droplet configuration in an energy efficient manner is an outstanding research problem of interdisciplinary relevance, having implications in widely varying areas ranging from biomedical diagnostics, thermal management to digital microfluidic technology. Here, we experimentally and theoretically demonstrate a simple yet energy efficient strategy for generating controlled vortices inside a surface droplet, by deploying interacting electrical and thermal fields over inter-digitated electrodes on an electrically wetted platform. Unlike the traditional electrically driven mechanisms, this strategy involves significantly low voltage (≤10 V) to induce rotational structures inside the droplet, by exploiting the strong spatial gradient of electrical properties on account of the prevailing thermal field as attributable to intrinsically induced Joule heating effects. Our experiments demonstrate that fluid velocities typically of the order of mm/s can be generated inside the droplet within the standard regimes of operating parameters, bearing far-reaching consequences towards enhancing internal mixing in multifarious droplet based microfluidic applications. An inherent integrability with the existing electrowetting on dielectric platforms renders the process ideal to be used in conjunction with digital microfluidic technology.

A facile methodology to create a wrinkled surface with a tailored topography is presented herein. The dependency of the elasticity of poly(dimethyl)siloxane (PDMS) on the curing temperature has been exploited to obtain a substrate with an elasticity gradient. The temperature gradient across the length of PDMS is created by a novel set-up consisting of a metal and insulator connected to a heater and the highest usable (no degradation of PDMS) temperature gradient is used. The time-dependent temperature distributions along the substrate are measured and the underlying physics of the dependence of the PDMS elasticity on the curing temperature is addressed. The PDMS substrate with the elasticity gradient is first stretched and subsequently oxidized by oxygen plasma. Upon relaxation, an ordered wrinkled surface with continuously varying wavelength and amplitude along the length of PDMS is obtained. The extent of hydrophobicity recovery of this plasma oxidized PDMS with varying elasticity has been studied. The change in the wavelength and amplitude of the regular patterns on the substrate can be controlled by varying operational parameters like applied pre-strain, plasma power and the heater temperature. It has been found that the spatial distributions of the topography and the hydrophobicity collectively decide the resultant wettability of the substrate. Such surfaces with gradients in the substructure dimensions demonstrate different wetting characteristics that may lead to a wide gamut of applications including droplet movement, cell adhesion and proliferation, diffraction grating etc.