Advanced reburning is a NO
x
reduction process wherein injection of a hydrocarbon fuel such
as natural gas downstream of the combustion zone is followed by injection of a nitrogen-containing
species such as ammonia. The authors recently reported a seven-step, 11-species reduced
mechanism for NO reduction by advanced reburning processes. However, inclusion of even a
seven-step reduced mechanism into a CFD code for turbulent combustion leads to substantial
computational demands. In this work, the authors have further simplified the kinetic mechanism.
A simpler four-step, eight-species reduced mechanism for NO reduction by advanced reburning
has been developed from a 312-step, 50-species full mechanism through the use of a systematic
reduction method. The four-step reduced mechanism is in good agreement with the full mechanism
for most laminar flow cases. It also agrees qualitatively with three sets of experimental data,
which show the influences of temperature, CO concentration, O2 concentration, and the ratio
(NH3/NO)in. It can be applied for coal-, gas-, and oil-fired combustion. The four-step reaction
sequence has been integrated into a comprehensive CFD combustion code for turbulent
combustion, PCGC-3. The method of integration is described. Several computations are reported
with the combined code to demonstrate the predictive behavior of the advanced reburning
mechanism in turbulent, pulverized coal combustion. The model calculations show the effects of
temperature and concentrations of CO, O2, and NH3 on NO reduction.
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