Where a licence is displayed above, please note the terms and conditions of the licence govern your use of this document. When citing, please reference the published version. Take down policy While the University of Birmingham exercises care and attention in making items available there are rare occasions when an item has been uploaded in error or has been deemed to be commercially or otherwise sensitive.

The cis-trans isomerization of CHS-Au-SCH driven by the tip of the scanning tunneling microscope is investigated at 77 K. CHS-Au-SCH anchored on the Au(111) surface with the S-Au-S axis parallel to the substrate functions as a molecular switch due to the flipping of the CH groups. The bonding between CHS-Au-SCH and Au(111) leads to asymmetric isomerization where one of the two methyl groups flips much more effectively than the other, despite the symmetry of CHS-Au-SCH. Our findings suggest the possibility of constructing similar molecular switches that can be operated at room temperature and a potential route for fine-tuning of molecular switches in future nanoscale electro-mechanical devices.

We report the discovery of bridge-bonded methylthiolate, SCH3, along the step edges of the Au(111) surface. Real-space imaging with a scanning tunnelling microscope reveals the presence of bridge-bonded SCH3 along both the [11[combining macron]0] and the [112[combining macron]] oriented step edges. The nearest neighbour distances of SCH3 along these steps are 2a and , respectively. The Au(111) terrace is covered with the usual CH3SAuSCH3 staples. The bridge-bonded alkanethiolate is expected to play a rather significant role in the formation of thiol-passivated Au nanoclusters because of the high fraction of atoms in similar low-coordination sites.

We study statically homogeneous Bose-Einstein condensates with spatially inhomogeneous interactions and outline an experimental realization of compensating linear and nonlinear potentials that can yield constant-density solutions. We illustrate how the presence of a step in the nonlinearity coefficient can only be revealed dynamically and consider, in particular, how to reveal it by exploiting the inhomogeneity of the sound speed with a defect-dragging experiment. We conduct computational experiments and observe the spontaneous emergence of dark solitary waves. We use effective-potential theory to perform a detailed analytical investigation of the existence and stability of solitary waves in this setting, and we corroborate these results computationally using a Bogoliubov-de Gennes linear stability analysis. We find that dark solitary waves are unstable for all step widths, whereas bright solitary waves can become stable through a symmetry-breaking bifurcation as one varies the step width. Using phase-plane analysis, we illustrate the scenarios that permit this bifurcation and explore the dynamical outcomes of the interaction between the solitary wave and the step.