This paper is the outcome of a community initiative to identify major unsolved scientific problems in hydrology motivated by a need for stronger harmonisation of research efforts. The procedure involved a public consultation through online media, followed by two workshops through which a large number of potential science questions were collated, prioritised, and synthesised. In spite of the diversity of the participants (230 scientists in total), the process revealed much about community priorities and the state of our science: a preference for continuity in research questions rather than radical departures or redirections from past and current work. Questions remain focused on the process-based understanding of hydrological variability and causality at all space and time scales. Increased attention to environmental change drives a new emphasis on understanding how change propagates across interfaces within the hydrological system and across disciplinary boundaries. In particular, the expansion of the human footprint raises a new set of questions related to human interactions with nature and water cycle feedbacks in the context of complex water management problems. We hope that this reflection and synthesis of the 23 unsolved problems in hydrology will help guide research efforts for some years to come. ARTICLE HISTORY

Abstract. The young water fraction F yw , defined as the proportion of catchment outflow younger than approximately 2-3 months, can be estimated directly from the amplitudes of seasonal cycles of stable water isotopes in precipitation and streamflow. Thus, F yw may be a useful metric in catchment inter-comparison studies that investigate landscape and hydro-climatic controls on streamflow generation. Here, we explore how F yw varies with catchment characteristics and climatic forcing, using an extensive isotope data set from 22 small-to medium-sized (0.7-351 km 2 ) Swiss catchments. We find that flow-weighting the tracer concentrations in streamwater resulted in roughly 26 % larger young water fractions compared to the corresponding unweighted values, reflecting the fact that young water fractions tend to be larger when catchments are wet and discharge is correspondingly higher. However, flow-weighted and unweighted young water fractions are strongly correlated with each other among the catchments. They also correlate with terrain, soil, and land-use indices, as well as with mean precipitation and measures of hydrologic response. Within individual catchments, young water fractions increase with discharge, indicating an increase in the proportional contribution of faster flow paths at higher flows. We present a new method to quantify the discharge sensitivity of F yw , which we estimate as the linear slope of the relationship between the young water fraction and flow. Among the 22 catchments, discharge sensitivities of F yw are highly variable and only weakly correlated with F yw itself, implying that these two measures reflect catchment behaviour differently. Based on strong correlations between the discharge sensitivity of F yw and several catchment characteristics, we suggest that low discharge sensitivities imply greater persistence in the proportions of fast and slow runoff flow paths as catchment wetness changes. In contrast, high discharge sensitivities imply the activation of different dominant flow paths during precipitation events, such as when subsurface water tables rise into more permeable layers and/or the river network expands further into the landscape.

The time that water takes to travel through the terrestrial hydrological cycle and the critical zone is of great interest in Earth system sciences with broad implications for water quality and quantity. Most water age studies to date have focused on individual compartments (or subdisciplines) of the hydrological cycle such as the unsaturated or saturated zone, vegetation, atmosphere, or rivers. However, recent studies have shown that processes at the interfaces between the hydrological compartments (e.g., soil‐atmosphere or soil‐groundwater) govern the age distribution of the water fluxes between these compartments and thus can greatly affect water travel times. The broad variation from complete to nearly absent mixing of water at these interfaces affects the water ages in the compartments. This is especially the case for the highly heterogeneous critical zone between the top of the vegetation and the bottom of the groundwater storage. Here, we review a wide variety of studies about water ages in the critical zone and provide (1) an overview of new prospects and challenges in the use of hydrological tracers to study water ages, (2) a discussion of the limiting assumptions linked to our lack of process understanding and methodological transfer of water age estimations to individual disciplines or compartments, and (3) a vision for how to improve future interdisciplinary efforts to better understand the feedbacks between the atmosphere, vegetation, soil, groundwater, and surface water that control water ages in the critical zone.

Record performance of high-power GaN/Al 0:14 -Ga 0:86 N high-electron mobility transistors (HEMT's) fabricated on semi-insulating (SI) 4H-SiC substrates is reported. Devices of 0.125-0.25 mm gate periphery show high CW power densities between 5.3 and 6.9 W/mm, with a typical power-added efficiency (PAE) of 35.4% and an associated gain of 9.2 dB at 10 GHz. High-electron mobility transistors with 1.5-mm gate widths (12 2 125 m), measured on-wafer, exhibit a total output power of 3.9 W CW (2.6 W/mm) at 10 GHz with a PAE of 29% and an associated gain of 10 dB at the 02 dB compression point. A 3-mm HEMT, packaged with a hybrid matching circuit, demonstrated 9.1 W CW at 7.4 GHz with a PAE of 29.6% and a gain of 7.1 dB. These data represent the highest power density, total power, and associated gain demonstrated for a III-Nitride HEMT under RF drive.

In this commentary, we summarize and build upon discussions that emerged during the workshop "Isotopebased studies of water partitioning and plant-soil interactions in forested and agricultural environments" held in San Casciano in Val di Pesa, Italy, in September 2017. Quantifying and understanding how water cycles through the Earth's critical zone is important to provide society and policymakers with the scientific background to manage water resources sustainably, especially considering the ever-increasing worldwide concern about water scarcity. Stable isotopes of hydrogen and oxygen in water have proven to be a powerful tool for tracking water fluxes in the critical zone. However, both mechanistic complexities (e.g. mixing and fractionation processes, heterogeneity of natural systems) and methodological issues (e.g. lack of standard protocols to sample specific compartments, such as soil water and xylem water) limit the application of stable water isotopes in critical-zone science. In this commentary, we examine some Published by Copernicus Publications on behalf of the European Geosciences Union. 6400 D. Penna et al.: Tracing terrestrial ecosystem water fluxes using stable isotopes of the opportunities and critical challenges of isotope-based ecohydrological applications and outline new perspectives focused on interdisciplinary research opportunities for this important tool in water and environmental science.