A newly discovered sedimentary accumulation of micrometeorites in the Sør Rondane Mountains of East Antarctica, close to the Widerøefjellet summit at $2750 m above sea level, is characterized in this work. The focus here lies on 2099 melted cosmic spherules larger than 200 lm, extracted from 3.2 kg of sampled sediment. Although the Widerøefjellet deposit shares similarities to the micrometeorite traps encountered in the Transantarctic Mountains, both subtle and more distinct differences in the physicochemical properties of the retrieved extraterrestrial particles and sedimentary host deposits are discernable (e.g., types of bedrock, degree of wind exposure, abundance of metal-rich particles). Unlike the Frontier Mountain and Miller Butte sedimentary traps, the size fraction below 240 lm indicates some degree of sorting at Widerøefjellet, potentially through the redistribution by wind, preferential alteration of smaller particles, or processing biases. However, the cosmic spherules larger than 300 lm appear largely unbiased following their size distribution, frequency by textural type, and bulk chemical compositions. Based on the available bedrock exposure ages for the Sør Rondane Mountains, extraterrestrial dust is estimated to have accumulated over a time span of $1-3 Ma at Widerøefjellet. Consequently, the Widerøefjellet collection reflects a substantial reservoir to sample the micrometeorite influx over this time interval. Petrographic observations and 3D microscopic CT imaging are combined with chemical and triple-oxygen isotopic analyses of silicate-rich cosmic spherules larger than 325 lm. The major element composition of 49 cosmic spherules confirms their principally chondritic parentage. For 18 glassy, 15 barred olivine, and 11 cryptocrystalline cosmic spherules, trace element concentrations are also reported on.Based on comparison with evaporation experiments reported in literature and accounting for siderophile and chalcophile element losses during high-density phase segregation and ejection, the observed compositional sequence largely reflects progressive heating and evaporation during atmospheric passage accompanied by significant redox shifts, although the influence of (refractory) chondrite mineral constituents and terrestrial alteration cannot be excluded in all cases. Twenty-eight cosmic spherules larger than 325 lm analyzed for triple-oxygen isotope ratios confirm inheritance from mostly carbonaceous chondritic precursor materials ($55% of the particles). Yet, $30% of the measured cosmic spherules and $50% of all glassy cosmic spherules are characterized by oxygen isotope ratios above the terrestrial fractionation line, implying genetic links to ordinary chondrites and parent bodies currently unsampled by meteorites. The structural, textural, chemical, and isotopic characteristics of the cosmic spherules from the Sør Rondane Mountains, and particularly the high proportion of Mg-rich glass particles contained therein, imply a well-preserved and representative new sedimentary micrometeorite collect...

Main group pallasite meteorites are samples of a single early magmatic planetesimal, dominated by metal and olivine but containing accessory chromite, sulfide, phosphide, phosphates, and rare phosphoran olivine. They represent mixtures of core and mantle materials, but the environment of formation is poorly understood, with a quiescent core–mantle boundary, violent core–mantle mixture, or surface mixture all recently suggested. Here, we review main group pallasite data sets and petrologic characteristics, and present new observations on the low‐MnO pallasite Brahin that contains abundant fragmental olivine, but also rounded and angular olivine and potential evidence of sulfide–phosphide liquid immiscibility. A reassessment of the literature shows that low‐MnO and high‐FeO subgroups preferentially host rounded olivine and low‐temperature P2O5‐rich phases such as the Mg‐phosphate farringtonite and phosphoran olivine. These phases form after metal and silicate reservoirs back‐react during decreasing temperature after initial separation, resulting in oxidation of phosphorus and chromium. Farringtonite and phosphoran olivine have not been found in the common subgroup PMG, which are mechanical mixtures of olivine, chromite with moderate Al2O3 contents, primitive solid metal, and evolved liquid metal. Lower concentrations of Mn in olivine of the low‐MnO PMG subgroup, and high concentrations of Mn in low‐Al2O3 chromites, trace the development and escape of sulfide‐rich melt in pallasites and the partially chalcophile behavior for Mn in this environment. Pallasites with rounded olivine indicate that the core–mantle boundary of their planetesimal may not be a simple interface but rather a volume in which interactions between metal, silicate, and other components occur.

No abstract

No abstract

Oxygen isotope ratios in magnetite can be used to study the origin of iron-oxide ore deposits. In previous studies, only 18O/16O ratios of magnetite were determined. Here, we report triple O isotope data (17O/16O and 18O/16O ratios) of magnetite from the iron-oxide–apatite (IOA) deposits of the Yazd and Sirjan areas in central Iran. In contrast to previous interpretations of magnetite from similar deposits, the triple O isotope data show that only a few of the magnetite samples potentially record isotopic equilibrium with magma or with pristine magmatic water (H2O). Instead, the data can be explained if magnetite had exchanged O isotopes with fluids that had a mass-independently fractionated O isotope composition (i.e., MIF-O), and with fluids that had exchanged O isotopes with marine sedimentary carbonate rocks. The MIF-O signature of the fluids was likely obtained by isotope exchange with evaporite rocks of early Cambrian age that are associated with the IOA deposits in central Iran. In order to explain the triple O isotope composition of the magnetite samples in conjunction with available iron isotope data for magnetite from the deposits, we propose that magnetite formed from magmatic fluids that had interacted with evaporite and carbonate rocks at high temperatures and at variable water/rock ratios; e.g., magmatic fluids that had been released into the country rocks of a magma reservoir. Additionally, the magnetite could have formed from magmatic fluids that had exchanged O isotopes with SO2 and CO2 that, in turn, had been derived by the magmatic assimilation and/or metamorphic breakdown of evaporite and carbonate rocks.