The mid-to late Holocene aridification pattern of NW Africa remains a matter of controversial debate. While many marine climate reconstructions indicate a relatively abrupt aridification at ∼5.5 ka BP, terrestrial palaeoclimate records rather show a spatially and temporally heterogeneous transition towards the modern arid state. To bridge conflicting evidence, we analysed high-resolution (sub-seasonal) ontogenetic oxygen isotope (δ 18 O) records and bulk 87 Sr/ 86 Sr ratios of bivalve shells and fish otoliths of estuarine-associated species. Samples were excavated from archaeological deposits formed during the mid-to late Holocene in a large palaeo-estuary east of the Banc d'Arguin, Mauritania. The mid-Holocene (∼5.2 ka BP) δ 18 O records indicated unrealistically high water temperatures when assuming a modern value for δ 18 O Seawater , suggesting a substantial input of isotopically lighter water to the study area. Respective salinity estimates consistently indicated persistent monsoonal discharge. Moreover, 87 Sr/ 86 Sr ratios of bivalve shells deviated considerably from the rather stable global seawater composition, further supporting the presence of significant terrestrial runoff between 5.0 and 5.3 ka BP. Altogether, our results support doubts regarding an abrupt termination of the African Humid Period (AHP) in the coastal areas of NW Africa, and show that fully marine conditions were established along the Banc d'Arguin by ∼3.0 ka BP.
Rationale The first‐row transition metals Cu, Ni, and Co show a strong binding affinity to natural organic matter. Compared to dissolved elements and stable water isotopes, they may be transported rapidly through the soil and host rock into caves in response to infiltration events. This study aims to assess the potential of transition metal ratios as indicators for infiltration changes in response to the seasonal and/or event‐based rainfall variation. Methods We developed a protocol to analyze Cu, Ni, and Co in the cave drip water using collision cell ICP‐QMS without extensive sample pretreatment. The high Ca matrix leads to significant isobaric interferences on all isotope masses. Our method includes a correction of these matrix effects and yields results with comparable accuracy and reproducibility to other published methods. We applied this protocol to drip water samples from Larga Cave (Puerto Rico) covering at least two full annual cycles between 2014 and 2019 on a bimonthly scale. Results The analysis of external reference materials yielded a reproducibility between 4.7% and 9.2% (relative standard deviation), validating the accuracy of the matrix correction method. The limit of detection is <0.04 ppb for Cu, <0.02 ppb for Ni, and <0.008 ppb for Co. The analysis of drip water samples from Larga Cave reveals pronounced changes of several orders of magnitude in all Element (El) to Ca, Cu/Ni, and Cu/Co ratios in response to seasonal infiltration changes. In addition, we observe a partly even stronger response after major tropical storms and heavy precipitation events of the period of record, for example, tropical storm “Bertha” (2014) and the category 5 hurricanes “Irma” and “Maria” (both 2017). Conclusions Transition metal ratios can be accurately measured in cave drip waters with high Ca matrix. At our tropical site, these are promising tracers of infiltration changes in response to changes in the amount of rainfall, providing the first step toward tropical cyclone reconstruction using trace elements in speleothems.
Abstract. A better understanding of ENSO dynamics is essential for modelling future climate change and its impacts on the ecosystems and lives of the inhabitants of the tropical Pacific islands, which face considerable environmental risk in the coming decades. This study reconstructs past ENSO dynamics using a multi-proxy approach applied to a stalagmite from Niue Island that covers the period 6.4–5.4 ka BP. δ18O and δ13C, trace-element concentrations and image analysis are linked to an age-depth model constrained by eight U/Th dates and a complete lamina count. Principal component analysis of the proxy time series reveals hydrological changes at seasonal scale that are expressed in differential stalagmite lamina growth and geochemical characteristics. Increased concentrations of host-rock derived elements (Mg/Ca and U/Ca) and higher δ18O and δ13C values are observed in the dark, dense calcite laminae that are deposited during the dry season, whereas during the wet season higher concentrations of soil derived elements (Zn/Ca, Mn/Ca) and higher δ18O and δ13C values are found in pale, porous calcite laminae. Greyscale intensity values measured along the stalagmite growth axis are used here as an indicator of colour and density changes of the alternating laminae, allowing for the construction of a further seasonality record which expresses the contrast between wet and dry seasons. The multi-proxy record from Niue shows seasonal cycles associated with hydrological changes controlled by the South Pacific convergence zone. Wavelet analysis of the greyscale record reveals that ENSO was continuously active during the depositional period, with two weaker intervals at 6–5.9 and 5.6–5.5 ka BP. ENSO activity is also observed in the seasonality record, but muted periods are more prolonged, and intervals of significant ENSO-band power are more episodic. Recurrence analysis of nonlinear behaviour shows the influence that ENSO activity exerts on seasonality patterns and allows us to quantify the predictability of the climate system. Our results suggest that recurrence in the seasonal cycle of rainfall was reduced during periods when ENSO activity was stronger, pushing the system towards stochastic conditions. The tipping points from stochastic to predictable conditions may represent transitions in the Tropical Pacific mean state.
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