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The aim of this work was to determine the importance of nodule formation on the dynamics of major and trace elements (TEs) along a Planosol toposequence developed in metamorphic parent material at La Châtre (Massif Central, France). The different horizons were sampled within three pits and analysed for major and trace element contents. The nodule-rich horizon was studied more closely. A simplified sequential extraction scheme, X-ray diffraction (XRD) and microscopic approaches were used in order to determine the individual phases containing TE in nodules.Along the slope, the nodule-rich horizon varies in thickness, is composed of different oxide fractions and has different scavenging efficiencies according to the TE considered. Iron was found to accumulate in the middle of the slope, while Mn accumulated at the base. The scavenging effect is only evident for Ni in profile 1. For Fe and Cu, it is maximal in profile 2 where the nodule-rich horizon is the thickest. For Pb and Mn, maximal scavenging effect is recorded for both profiles 2 and 3, in the lowest part of the slope. Cr is not accumulated at all. This was related to the water dynamic and the hydromorphic conditions prevailing along the slope.Results obtained by sequential extractions and associated X-ray diffraction on the different nodule size fractions and those obtained by electron microprobe allow inference of the TE distribution in nodules. Nodules were mainly composed of three to four types of cements surrounding grains of quartz, feldspars, micas and accessory minerals: iron-rich cements, Si-and Al-rich cements, Mn-rich cements and Ti-rich cements in places.The iron-rich cements consist of poorly crystalline goethite and possibly some ferrihydrite. Ferrihydrite is associated with Cr as demonstrated by extractions. Goethite contained Mn and most of the TE extracted except for Ni and Pb.Fine-grained Si-and Al-rich cements were also observed. They contain variable amounts of Ti and Mn. 0016-7061/$ -see front matter D Geoderma 125 (2005) 11 -24 www.elsevier.com/locate/geodermaMn-rich cements were not present in all the nodules and were mainly linked to the dark zones of the nodules. The nature of these Mn oxides could not be determined. They were found to contain Co, Ni, Cu and probably Pb. D

International audienceSoil erosion is one of the main factors influencing land degradation and water quality at the global scale. Identifying the main sediment sources is therefore essential for the implementation of appropriate soil erosion mitigation measures. Accordingly, caesium-137 (137Cs) concentrations were used to determine the relative contribution of surface and subsurface erosion sources in a lowland drained catchment in France. As 137Cs concentrations are often dependent on particle size, specific surface area (SSA) and novel thorium (Th) based particle size corrections were applied. Surface and subsurface samples were collected to characterize the radionuclide properties of potential sources. Sediment samples were collected during one hydrological year and a sediment core was sampled to represent sediment accumulated over a longer temporal period. Additionally, sediment from tile drains was sampled to determine the radionuclide properties of sediment exported from the drainage network. A distribution modelling approach was used to quantify the relative sediment contributions from surface and subsurface sources. The results highlight a substantial enrichment in fine particles and associated 137Cs concentrations between the sources and the sediment. The application of both correction factors reduced this difference, with the Th correction providing a more accurate comparison of source and sediment samples than the SSA correction. Modelling results clearly indicate the dominance of surface sources during the flood events and in the sediment core. Sediment exported from the drainage network was modelled to originate predominantly from surface sources. This study demonstrates the potential of Th to correct for 137Cs particle size enrichment. More importantly, this research indicates that drainage networks may significantly increase the connectivity of surface sources to stream networks. Managing sediment transferred through drainage networks may reduce the deleterious effects of suspended sediment loads on riverine systems in similar lowland drained agricultural catchments

Models of soil genesis are potentially of great importance in assessing the effects of global change on ecosystems, and may also contribute to our understanding of soil genetic processes. Many quantitative models have so far focused on individual soil genetic processes and are difficult to extrapolate to the landscape scale. A few attempts have been made to model soil evolution as a whole from a pedologic perspective. This study develops a quantitative model of soil formation at the profile scale, taking into account major soil-forming processes. These include physical and chemical weathering of primary minerals, strain processes, and bioturbation. The model allows the quantification of the evolution of the particle size, mineral composition and bulk density of the soil. The model is applied with varying values of input parameters, and is compared with actual soil genetic processes. Running the model results in the formation of stone-layered soil profiles. Stone-line formation by means of bioturbation, as already described in the literature, seems to be adequately simulated. Planned improvements of the model include implementation of other major soil genetic processes such as leaching, organic matter influence, etc. This model will then have to be implemented spatially considering particularly redistribution processes, to reproduce soil formation at the landscape scale.