Sour-gas absorption is the main unit operation used in refineries and petrochemical and natural gas processing plants for the effective reduction of climate-wrecking gases, mainly CO 2 and H 2 S. Absorption is typically accomplished in an aqueous solvent mixture. The solvent mixture is vastly dependent on the application range; it might contain chemical solvents (amines), activators, and physical solvents. In this work, the vapor−liquid equilibria for absorption of the sour gases CO 2 and H 2 S was investigated in systems containing the chemical solvent methyl diethanolamine (MDEA) and the physical solvents tetrahydrothiophene-1,1-dioxide (sulfolane) or the ionic liquid 1-butyl-3-methylimidazolium acetate. The solubilities of CO 2 and H 2 S were predicted and validated using experimental literature data in a broad range of temperature (313−373 K), sour-gas loading (up to 2 moles gas per moles of MDEA), and pressure (up to 180 bar) at constant MDEA weight fraction (20.9 wt %) and sulfolane weight fraction (30.5 wt %). The equation-of-state electrolyte perturbed-chain statistical associating fluid theory (ePC-SAFT) was utilized in this work for the predictions combined with the Born term to physically correctly describe the Gibbs energy of solvation of ions in the aqueous mixture of chemical and physical solvents; this was introduced in a recent work [Bulow, M. et al. Fluid Phase Equilib. 2021, 535, 112967]. Using this approach allowed reducing the total number of binary interaction parameters in these systems of maximum 11 species to a minimum; these parameters were fitted exclusively to data of binary mixtures. The ePC-SAFT predictions of the gas solubility were most accurate at low sour-gas loadings and high temperatures. This work provides a thermodynamic framework for the solvent selection for sour-gas absorption in a broad range of conditions. This enables a realistic decrease in experimental effort for solvent selection in sour-gas absorption.
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