This study describes synthesis and detailed characterization of 2D and 3D mesocrystalline films produced by self‐assembly of iron oxide (magnetite) truncated nanocubes. The orientational relations between nanocrystals within the superlattice are examined and atomistic models are introduced. In the 2D case, two distinct superstructures (i.e., translational order) of magnetite nanocubes can be observed with p4mm and c2mm layer symmetries while maintaining the same orientational order (with [100]magnetite perpendicular to the substrate). The 3D structure can be approximated by a slightly distorted face‐centered cubic (fcc) superlattice. The most efficient space filling within the 3D superstructure is achieved by changing the orientational order of the nanoparticles and following the “bump‐to‐hollow” packing principle. Namely orientational order is determined by the shape of the nanoparticles with the following orientational relations: [001]SL||[310]magnetite, [001]SL||[301]magnetite, [001]SL||[100]magnetite. Overall the presented data provide a fundamental understanding of a mesocrystal formation mechanism and their structural evolution. Structure, composition, and magnetic properties of the synthesised nanoparticles are also characterized.

Elena Sturm (née Rosseeva), Helmut Cölfen, and co‐workers present a study that is focused on the structural evolution of 2D and 3D self‐assembled magnetite mesocrystalline films. In article 1600431, it is shown that the orientational order in 2D and 3D superstructures is different. In 2D superstructure nanoparticles prefer to keep the same orientation, while in 3D a certain tilt is necessary to achieve the most efficient space filling, in line with the well‐known “bump‐to‐hollow” packing principle.

The paper proposes a solution to the problem of selecting the bandwidth capabilities of digital communication channels of a transport communication network taking into account the imbalance of data traffic by priorities. The algorithm for selecting bandwidth guarantees the minimum costs associated with renting digital communication channels with optimal bandwidth, provided that the requirements for quality of service of protocol data blocks of the first, second, and k-th priority in an unbalanced in terms of priorities transport communication network are met. At the first stage of solving the problem, using the method of Lagrange multipliers, an algorithm for selecting the capacities of digital communication channels for a balanced in terms of priorities transport network was developed. High performance of this algorithm was ensured by applying algebraic operations on matrices (addition, multiplication, etc.). At the second stage of solving the problem, using the generalized Lagrange multipliers method, we compared the conditional extrema of the cost function for renting digital communication channels for single active quality of service requirements for protocol data blocks, for all possible pairs of active quality of service requirements for protocol data blocks, for all possible triples of active requirements for the quality of service of protocol data units, and so on up to the case when all the requirements for quality of service maintenance of protocol data units are active simultaniously. At the third stage of solving the problem, an example of selecting the bandwidth capabilities of digital communication channels of the unbalanced by priorities transport network consisting of eight routers serving protocol data blocks of three priorities was considered. At the fourth stage of the solution of the problem of the choice of carrying capacities the estimation of efficiency of the developed algorithm by a method of simulation modeling was carried out. To this end, in the environment of the network simulator OMNet ++, the unbalanced in terms of priority transport communication network consisting of eight routers connected by twelve digital communication channels with optimal bandwidth was investigated.

The anomalies in diffusion behavior of compositionally modulated structuresin ordering systems W/Sb and Co/Pt are discussed. There are stable subnanometer modulated structures in W/Sb alloys. It has allowed to construct normal incidence X-ray mirrors. Co/Pt alloys are characterised by arising of self-organizated modulated structures with d=3.8 - 4.2 nm.