During the irradiation of structural elements with neutrons, ions, electrons, the mechanical properties of materials change. The neutron irradiation is of particular interest. Therefore, the relevance of the study is beyond doubt. The main purpose of this paper is to investigate the vibration damping of a circular composite viscoelastic plate under neutron irradiation. According to existing concepts, two mechanisms of accelerated radiation creep are possible. An initial-boundary value problem of free vibrations damping in a circular linearly viscoelastic sandwich plate under neutron irradiation is considered. It is determined that when the frequency of the perturbing force coincides with higher frequencies of natural oscillations, the periodicity is blurred, although the amplitude of oscillations increases and, in this case, a "false resonance" is observed. An analytical solution is obtained using the averaging method in dynamic viscoelasticity problems. The logarithmic decrement of oscillations is investigated numerically. Its dependence on the intensity of the neutron flux is revealed.
When solving the problems of coupled heat transfer between viscous flows and streamlined bodies under the conditions of aerodynamic heating of aircraft, it is necessary to overcome significant difficulties. They associated primarily with determining the boundary conditions. The paper investigates the joint (coupled) heat transfer between a heat and gas dynamic boundary layer and an anisotropic strip under conditions of aerodynamic heating based on the obtained analytical solution of the second initial boundary value problem of thermal conductivity in an anisotropic strip with arbitrary boundary conditions. Since the system of equations of the gasdynamic boundary layer is essentially nonlinear, mainly numerical methods are used to solve it. For an incompressible boundary layer near the critical point of a blunt wedge, an analytical solution is obtained to determine the components of the velocity vector, density, temperature, and heat fluxes. The closed-form solution to the conjugate problem was received in the form of a Fredholm integral equation of second kind. The results of numerical experiments are obtained and analyzed.
In this work, we studied a biocompatible hybrid material based on iron (III) and muconic acid oxoclusters. It has been shown that coordination polymers are a promising class as functional materials for various purposes (as sorbents, catalysts, conductors, storage materials, etc.). The adsorption capacity of the obtained adsorbent for removing dyes from the prepared solution was in the following order: CR> MB> MV. From the results of the study, we can conclude that the dye Congo red is best suited for adsorption by the coordination polymer. The maximum absorption of the dye on organometallic coordination polymers occurs in the pH range 5 - 7 with adsorption of ~ 90%, which is important for the potential practical application of such coordination polymers as carriers for drug delivery.
In this study, two types of ligands were introduced onto the surface of magnetite nanoparticles by hydrolysis and condensation of organosilicon reagents: organosilane-tetraethoxysilane (TEOS) and aminoorganosilane - aminopropyltriethoxysilane (APTES). It is shown that coatings based on SiO2 solve a double problem: first, they prevent the aggregation of nanoparticles and the oxidation of magnetite; secondly, they allow the surface to be modified with various specific ligands for biomedical applications due to terminal groups. It was shown, that after the modification of TEOS and APTES (in argon and in air), the Fe3O4 content decreases to 66, 42, and 36%, respectively. The formation of a silicon framework on the magnetite surface due to Fe-O-Si and Si-O-Si bonds was determined by IR spectroscopy. The identification of surface amino groups is complicated due to the superposition of absorption bands of NH2- and OH-groups. This opens new prospective for creation of tailored nanocomposites containing magnetite nanoparticles. These materials can be further used as sorbents for various applications.
Tests on bending are one of the effective ways to experimentally determine the elasticity and shear moduli. An important task in the implementation of composite materials in aerospace structures is the development of methods for determining the physical and mechanical characteristics of materials. The paper presents of tests for three-point bending of samples of metal-polymer composite material "GLAss-REinforced" Fibre Metal Laminate (GLARE) are presented. Examined samples, consisting of 17 layers, for which apparent interlayer strength of the results of tests on three-point bending was established by the method of "short beam". It was established that for the studied samples, interlayer shear mechanisms were realized at the ratio of dimensions of length to thickness of at least 10. Localization of fracture occurs in the area of the central layer, which corresponds to the requirements of standards for conducting tests of the method of short beams. Nonetheless, such GLARE tests are always accompanied by the occurrence of significant plastic deformations associated with the presence of aluminum layers in the structure of the material. With the elongation of samples of more than 10, a fracture mechanism is realized in them, during which delamination and loss of stability of the outer layers on the compressed side of the sample occur. When the elongation of samples of less than 4 four is implemented in samples takes place, the mechanism of destruction of indentation type with large nonlinear deformations. According to the test results, the dependence of the realised fracture mechanisms on the elongation of the samples is determined.
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