Composite materials were successfully made out of plant oil-based resin and northern red oak (Quercus robur) leaves collected in the fall. The viscosities of the bio-based resins (MAESO and MAELO) were suited to high temperature resin transfer molding (RTM) and vacuum-assisted resin transfer molding (VARTM) processing. The leaves have a waxy epidermal surface layer that needs to be dewaxed prior to use in a composite part. We used different treatments (such as benzene-ethanol, boiling water, and strong detergent) to dewax the leaves; all three methods seem to give good results; but boiling water and strong detergent were considered the best treatments for the dewaxing of leaves and boiling water was considered the greenest dewaxing method. The compatibility between the resin and the leaves was improved with a silane treatment which resulted in composites with higher mechanical stiffness than the resin itself. With 10 wt % leaves, we obtained an improvement in the composite modulus of about 14% from which we could estimate the leaf modulus at about 5.3 GPa. An alternative method to produce biocomposites from leaves without the need for silane treatments consists in carbonizing the leaves first at 215 C for 12 h, and then at 450 C for 1 h. The composites made with leaves and bioresins derived from functionalized triglycerides have the potential for use in high volume applications with low costs such as housing, construction, civil infrastructure, toys, and furniture. The use of leaves as a biocomposite filler has several advantages including (a) reduced cost, (b) improved properties of the resin, (c) composites with high bio content, (d) removal of a waste material with subsequent prevention of burning with attendant health hazards, and (e) interesting design aesthetics for interior and exterior decoration.
The European Spongy moth, Lymantria dispar (L.) (Lepidoptera: Erebidae), is an abundant species found in oak woods in Central and Southern Europe, the Near East, and North Africa and is an important economic pest. It is a voracious eater and can completely defoliate entire trees; repeated severe defoliation can add to other stresses, such as weather extremes or human activities. Lymantria dispar is most destructive in its larval stage (caterpillars), stripping away foliage from a broad variety of trees (>500 species). Caterpillar infestation is an underestimated problem; medical literature reports that established populations of caterpillars may cause health problems to people and animals. Inflammatory reactions may occur in most individuals after exposure to setae, independent of previous exposure. Currently, chemical and mechanical methods, natural predators, and silvicultural practices are included for the control of this species. Various insecticides have been used for its control, often through aerial sprayings, which negatively affect biodiversity, frequently fail, and are inappropriate for urban/recreational areas. However, bioinsecticides based on various microorganisms (e.g., entomopathogenic viruses, bacteria, and fungi) as well as technologies such as mating disruption using sex pheromone traps have replaced insecticides for the management of L. dispar.
Biocomposites have emerged as promising alternative materials for the aviation industry. However, there is a limited body of scientific literature addressing the end-of-life management of biocomposites. This article evaluated different end-of-life technologies for biocomposite recycling in a structured, five-step approach applying the innovation funnel principle. First, ten end-of-life (EoL) technologies were compared in terms of their circularity potential and technology readiness levels (TRL). Second, a multi-criteria decision analysis (MCDA) was carried out to find out the top four most promising technologies. Afterwards, experimental tests were conducted at a laboratory scale to evaluate the top three technologies for recycling biocomposites by analysing (1) three types of fibres (basalt, flax, carbon) and (2) two types of resins (bioepoxy and Polyfurfuryl Alcohol (PFA) resins). Subsequently, further experimental tests were performed to identify the top two recycling technologies for the EoL treatment of biocomposite waste from the aviation industry. Finally, the sustainability and economic performance of the top two identified EoL recycling technologies were evaluated through life cycle assessment (LCA) and techno-economic analysis (TEA). The experimental results, performed via the LCA and TEA assessments, demonstrated that both solvolysis and pyrolysis are technically, economically, and environmentally viable options for the EoL treatment of biocomposite waste from the aviation industry.
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