Solid-state reactions of SiC/W-25Re alloy and SiC/Ti/W-25Re alloy are investigated under the hightemperature annealing at1 500 C. The interface reaction layer between SiC and W-25Re alloy is composed of WC-WSi 2 -W 5 Si 3 -W-Re sigma phase -dendrite microstructure. Solid-state reactions between W and SiC form two types of W-silicides and the relative depletion of W brings formation of the W-Re sigma phase. In order to prevent direct interfacial reactions, Ti layer is intercalated as a secondary buffer layer. Compared to the original interface, thicknesses of both reaction layer and dendrite layer are significantly decreased. Although the thermal reaction of Ti and W brings inhomogeneous characteristics, the proposed functionally graded structure is expected to enhance the thermal stability.