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[1] From a small meromictic lake, we present observations of a circulation pattern that has not been documented in the limnological literature before. While surface cooling drives a vertical circulation of the upper water layer (mixolimnion), the deeper water layer (monimolimnion) is not included because of its higher salt concentration. However, double diffusion (higher diffusivity of heat than of dissolved substances) facilitates the faster escape of heat from the monimolimnion compared to dissolved substances during cold periods. As a consequence, interfacial cooling drives a vertical circulation within the monimolimnion without breaking the stratification toward the mixolimnion. In the presented case, the geochemical setting does not permit dissolved substances to accumulate in the mixolimnion. As a consequence, the system approaches the case of two immiscible layers in thermal contact. Below the interface, a convection layer is formed that exceeds the staircase layer thickness of double diffusion when conservative salts are involved. Finally, the entire lake circulates as two separate convection layers. This has a decisive impact on the formation of gradients and the redistribution of dissolved substances in lakes.

Density differences are the key parameter for stratification stability. We used data from the iron-meromictic Waldsee, Germany, a lignite mine pit lake, to quantify the contribution of single solutes to water density and analyzed the density gradient. Iron meromictic lakes maintain their density gradient through chemical reactions. Hence, quantifying the contributions of separate solutes is essential for understanding the entire process. Based on solute concentrations and literature values of partial molal volumes, substance specific density contributions were quantitatively evaluated. Then, by direct measurements of the density of IHSS Waskish peat fulvic acid, we quantified the density contribution of dissolved organic carbon (DOC). While several solutes contributed to the density throughout the water column, only those substances that occurred at higher concentrations in the anoxic monimolimnion than in the oxic mixolimnion were crucial to sustaining the density difference between the two layers. In Waldsee, the density difference between monimolimnion and mixolimnion was attributed to dissolved Fe 2? (0.23 g/L, resulting in a 45 % of the density difference due to solutes) and to the carbonate system (HCO 3 -, about 0.16 g/L and CO 2 , 0.03 g/L) while Ca 2? and DOC delivered only a small contribution. In summer, total density differences were dominated by temperature differences; during winter, solutes sustained meromixis. Finally, we present a complete list of specific density fractions for basically all of the density-relevant substances in fresh waters.

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