Chlorierung der Alkoxyamine (I) mit tBuOCl liefert die N‐Chlor‐N‐alkoxyamine (II), die mit den Alkoholen (III) in Gegenwart von Et3N als Base [zur Synthese von (IVa) wird Na‐methylat als Base verwendet] unter nucleophiler Substitution zu den N,N‐Dialkoxyaminen (IV) reagieren; neben (IVd) bzw. (IVf) entstehen die Azoxy‐Verbindungen (Va) ( 12% Ausb.) bzw. (Vb) ( 26%).
1993 cycloaddition reactions cycloaddition reactions O 0070 34 -068 Reaction Potentiality of N-Aryldichloromaleimides in Diene Reactions with Cyclopentadiene and 1,3-Cyclohexadiene. -Kinetic parameters of cycloaddition reaction of a number of N-aryldichloromaleimides such as (I) with cyclopentadiene and cyclohexadiene are investigated. -(NAGIEV, YA. M.; SAKUILOVA, YA. D.; BAGIROV, SH. T.; SHNULIN, A. N.; ADIGEZALOV, V. A.; NASIBOV, SH. S.; PASHAEV, B. K.; SHAKHTAKHTINSKII, T. N.; Zh.
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