ZIF-12 is converted to Co/N-CNTs at 950 °C under an argon atmosphere. The obtained hybrid nanocomposite is used for LIBs application as an anode material with superior charge storage performance.

A single-step solution-based strategy is used to obtain 2D Janus-like free-standing ultrathin nanosheets build from two structurally unrelated species, that is, polyoxomolybdate (POM) and CoO. A controlled 2D-to-1D morphological transition was achieved by judiciously adjusting the solvent choice. These POM-CoO heterostructures can behave as an ideal catalyst for the epoxidation of styrene. Benefiting from their amphiphilic nature, these 2D POM-CoO nanosheets have also been used as surfactant to emulsify immiscible solvents. It is anticipated that structurally diverse polyoxometalates will offer promise as design elements for variety of structurally and compositionally tunable van der Waals integrated heteromaterials having a broad range applications. Figure 1. a) PCNSs formation model. b) TEM, c) AFM, d) HRTEM and SAED pattern, e) elemental mapping through EDX, and f) XRD pattern of as-synthesized PCNSs. Supporting information and the ORCID identification number(s) for the author(s) of this article can be found under: https://doi.

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