This study presents an intelligent voltammetric system consisting of a personal computer and a digital voltammeter with VXIbus architecture of system control board, voltammetric measurement board and electrode evaluation board. System is designed to provide superior, comprehensive, versatile and convenient storage, analysis and display of electrochemical and voltammetric waveforms. Voltammeter is capable of stand-alone operation or direct PC control through a Labview program and serial communication interface. Stand-alone offers several general voltammetric functions such as electrochemical treatment and evaluation of electrodes and experimental voltammetry. PC connection gives additional functions such as automatic scanning of oxidation potential, expanded storage and processing of experimental data, arbitrary voltammetric waveform parameters, etc. Standalone uses microcontroller and three-bus structure, with EEPROM storing waveform parameters, experimental data and machine code program downloaded from PC. Electrode evaluation board tests electrode quality by measuring electrode equivalent resistance and capacitance, requiring only one button to perform the entire procedure. Minimum potential unit is 1 mV, at which setting the voltage range is −2.05 to +2.05 V. At a minimum unit of 4.9 mV, the voltage range is −10 to +10V. Experimental results are presented using carbon fiber electrode to measure the dopamine concentration in PBS solution, showing minimum oxidation current can be measured to less than 10 pA, with a minimum detectable bulk concentration of less than 10 ppb. The combination of PC with stand-alone voltammeter offers high-speed, precision, automation, versatility and portability, while the VXIbus architecture allows easy expansion capability.

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