The sulfur transformation during pyrolysis and gasification of three kinds of coals was studied and the release of H2S and COS during the process was examined. During pyrolysis, besides the property of coal, reaction temperature is the most important factor that affects the sulfur removal. The main sulfur-containing gases is H2S, the ratio of sulfur-containing gases amount to total sulfur amount in coal reaches 25.8% for LS coal, 31.8% for YT coal and 13.1% for HJ coal, respectively. During CO2 gasification, compared with pyrolysis and steam gasification, there are more COS and less H2S formation, because CO could react with sulfide to form COS. During steam gasification, only H2S formation and no COS detected, because H2 has stronger reducibility to form H2S than CO. And the formation rate of sulfur during gasification is consistent with the gasification reactivity of three coal chars, indicated that coal rank is the major factor which affects the sulfur distribution during gasification.

The CO2 gasification of three coal chars were investigated for determining the gasification reactivity and the kinetic parameters. Experiments were conducted in a fluidized-bed reactor at temperature of 1173 k, 1273 k and 1373 k at atmospheric pressure. Gasification kinetic parameters of the samples were determined using Homogeneous model and shrinking-core model. It is found that the gasification reaction under chemical-reaction-rate control, the gasification reactivity of coal char are strongly dependent on the rank of coals and gasification temperature. Both models could describe CO2 gasification equally well, these kinetic values are comparable with the reported in the literature for the other chars under chemical control conditions.

A kind of novel ash-calcium-powder internal wall coating was successfully prepared. The stability problem was resolved by adding the stabilizer synthesized in our own laboratory. The effect of vinyl acetate ester-ethylene (VAE) emulsion contents on the property of scrub resistance was studied. And the effect of ash-calcium-powder contents on the property of scrub resistance and contrast ratio were discussed. The results indicate that the scrub resistance increase with increasing the content of ash-calcium-powder or VAE emulsion. Also the scrub resistance is effected by the filming time. And it is shown that the longer, the better the scrub resistance.