The paper studied the effect on the performance of organic polymer solar cells at the active layer based on P3HT/PCBM from the addition of a solid derivative of nitrobenzene, 1-Bromo-4-Nitrobenzene, carried out experiment on 1-Bromo-4-Nitrobenzene doped with different doses in P3HT/PCBM active layer, and comparatively analyzed the performance parameters, absorption intensity, external quantum efficiency, fluorescence intensity, morphology characterization, and transient absorption of devices under different doses. Results showed that the organic polymer solar cells reached the maximum energy conversion efficiency, the energy conversion efficiency was improved from 2.2% to 3.4%, with an increase of 54 %, when the additive volume of 1-Bromo-4-Nitrobenzene was 25wt%. Addition of 1-Bromo-4-Nitrobenzene helped to improve the photoelectric conversion efficiency of organic polymer solar cells.

The J-V curve measurment and AFM technology were applied to study the relationship between P3HT:PCBM heterojunction film solar cell devices photovoltics parameter and blend solution concentration and annealed time of this device. The Voc, Jsc, FF and PCE of device were obtained from the device prepared by three blend solution concentration respectively. Data show that with increasing solution concentration PCE of solar cell device do not always improve and it achieves maximum when concentration is 20 mg/mL. Result indicates that only when solar cell device has active layer with proper thickness its performance will achieve the best effect. Additionally, photovoltaic parameters from four sample prepared by different annealed time were obtained also. Results indicate that the device with proper annealed time of 20 min at 130°C can achieve the best effect.