Abstract. The hardening and microstructural evolution during ageing of a Al-1.2Cu-0.5Mg and a Al-1.2Cu-1.2Mg (at.%) alloy has been investigated. Artificial ageing at 150°C of stretched and naturally aged samples initially (up to about 48 h) leads to very limited further strengthening, but ageing at 190°C results a quick increase in strength. Detailed microstructural investigation using differential scanning calorimetry, transmission electron microscopy and three-dimensional atom probe demonstrated that hardening at 150ºC is mostly dominated by the formation of solute clusters with varying compositions and plate-like zones rich in copper at early stages of ageing (t<24h) and by the formation of S phase at the later stages of ageing. At higher 190ºC no zones or clusters form and the ageing is dominated by the formation of S precipitates.
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