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In this paper, the discrete phase model (DPM) was introduced to study the fuel injector cavitations process and the macro spray characteristic of three different types of nozzle spray shape with diesel and hybrid biofuel blend for several injection pressures and backpressures. The three types of nozzle spray shapes used were circle, elliptical A type, and elliptical B type. The cavitations’ flows inside the injector nozzles were simulated with Computer Fluid Dynamics (CFD) simulations using the cavitations mixture approach. The effect of nozzle spray shape towards the spray characteristic of hybrid biofuel blends is analyzed and compared with the standard diesel. Furthermore, a verification and validation from both the experimental results and numerical results are also presented. The nozzle flow simulation results indicated that the fuel type did not affect the cavitation area vastly, but were more dependent on the nozzle spray shape. In addition, the spray width of the elliptical nozzle shape was higher as compared to the circular spray. Moreover, as the backpressure increased, the spray width downstream increased as well. The spray tip penetration for the elliptical nozzle shape was shorter than the circular nozzle shape due to circular nozzles having smaller nozzle widths and lesser spray cone angles. Thus, this resulted in smaller aerodynamic drag.