Optimizing the performance and understanding the mechanism of metal oxide catalysts in the oxidative coupling of methane (OCM) is one of the most important projects in industrial catalysis. Here, we report an intelligent approach to screen Na−Mn−W/SiO2 catalysts for the OCM reaction via ink‐jet printing and multidimensional group testing. The ink‐jet‐printing‐assisted (IJP‐A) synthetic methodology ensured a fast synthesis of 1536 catalysts that were evaluated in 24 tests via a multidimensional group testing strategy (m‐GT). After two‐round synthesis‐and‐screening processes, several excellent groups with different composition space were screened out. Among the excellent catalysts, the OCM performance of Na−Mn−W/SiO2 catalyst with higher Na, Mn and W content (G3 and G7) was less sensitive to its constituent than that of Na−Mn−W/SiO2 catalyst with lower Na, Mn and W content (G1). These results indicated the sensitivity of performance to its Na, Mn and W content decreased in larger Na, Mn and W spaces, consistent with the complex homogeneous/heterogeneous reaction mechanism and multi‐active sites. A series of Na−Mn−W/SiO2 formulas with good performance also provide a reasonable explanation to its excellent stability for the OCM reaction. In addition, this intelligent optimization in total space offers a pathway to study the multicomponent metal oxide catalyst in the OCM reaction.

An intelligent approach was developed to screen Na−Mn−W/SiO2 catalysts for oxidative coupling of methane (OCM). Effective compositions other than the frequently used composition were successfully found. The wide range of optimal compositions allowed a fluctuation of composition during the reaction, which led to excellent stability in the OCM. More information can be found in the Full Paper by Shihui Zou, Jie Fan et al. on page 487 in Issue 5, 2018 (DOI: 10.1002/cnma.201800019).