In this study, seven types of first-order and one-variable grey differential equation model (abbreviated as GM (1, 1) model) were used to predict hourly particulate matter (PM) including PM 10 and PM 2.5 concentrations in Banciao City of Taiwan. Their prediction performance was also compared. The results indicated that the minimum mean absolute percentage error (MAPE), mean squared error (MSE), root mean squared error (RMSE), and maximum correlation coefficient (R) was 14.10%, 25.62, 5.06, and 0.96, respectively, when predicting PM 10 . When predicting PM 2.5 , the minimum MAPE, MSE, RMSE, and maximum R value of 15.24%, 11.57, 3.40, and 0.93, respectively, could be achieved. All statistical values revealed that the predicting performance of GM (1, 1, x (0) ), GM (1, 1, a), and GM (1, 1, b) outperformed other GM (1, 1) models. According to the results, it revealed that GM (1, 1) GM (1, 1) was an efficiently early warning tool for providing PM information to the inhabitants.