The microwave dielectric properties and the microstructures of (Mg1−xZnx)2TiO4 ceramics prepared by the conventional solid‐state route were investigated. Lattice parameters were also measured for samples with different x. As x increased from 0 to 0.05, the Q×f of the specimen can be promoted from 150 000 GHz to a maximum 275 300 GHz. It also showed a remarkable lowering in the sintering temperature (∼100°C). Ilmenite‐structured (Mg0.95Zn0.05)TiO3 was detected as a second phase. The coexistence of the second phase, however, is not harmful to the dielectric properties of the specimen because it possesses compatible ones. A fine combination of microwave dielectric properties (ɛr∼15.48, Q×f∼275 300 GHz, τf∼−34 ppm/°C) was obtained for (Mg0.95Zn0.05)2TiO4 specimen sintered at 1330°C for 4 h. It is proposed as a very promising dielectric material for low‐loss microwave and millimeter wave applications.
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