In the present work, gold (Au), silver (Ag), and copper
(Cu) based
mono- and bimetallic NPs are prepared using a cost-effective facile
wet chemical route. The pH for the synthesis is optimized in accordance
with the optical spectra and supported by the finite difference time
domain simulation studies. FESEM and TEM micrographs are used to analyze
the morphology of the prepared nanoparticles. TEM images of bimetallic
nanoparticles (BMPs) verified their bimetallic nature. XRD studies
confirmed the formation of fcc-structured mono- and bimetallic NPs.
Photoluminescence studies of the as-synthesized NPs are in good agreement
with the previous publications. These synthesized NPs showed enhanced
catalytic activity for the reduction/degradation of 4-nitrophenol,
rhodamine B, and indigo carmine dyes in the presence of sodium borohydride
(NaBH
4
) compared to NaBH
4
alone. For the reduction
of 4-nitrophenol, Au, Cu, and CuAg nanoparticles exhibited good catalytic
efficiency compared to others, whereas for the degradation of rhodamine
B and indigo carmine dyes the catalytic efficiency is comparatively
high for CuAg BMPs. Furthermore, the antibacterial assay is carried
out, and Ag NPs display effective antibacterial activity against
Klebsiella pneumoniae
,
Salmonella
ser.
Typhimurium,
Acinetobacter baumannii
,
Shigella
flexneri
, and
Pseudomonas aeruginosa
.
Volatile organic compounds (VOCs) are harmful to human beings and
animals. VOCs include a carbon compound and its derivatives. VOCs
irritate the eyes, ears, and throat, ahigh concentration of VOCs may
cause cancer; also, it affects the central nervous system. A concentration
below 0.3 mg/m3 is harmless, above which it is harmful
to human beings. The present work discusses the detection of harmful
VOCs using a lab-made portable device setup. Hydrothermally synthesized
tin oxide (SnO2) nanocubes are used as an active material
for VOC detection. The SnO2 pellet is prepared using a
hydraulic press method and is used in the portable setup. Temperature-dependent
VOC detection is carried out using a microheater. An external potential
is applied to the microheater, which stimulates the active material
to sense ethanol at 40 °C. SnO2 and EA deposited on
graphite interdigitated electrodes projected on cellulose are used
to detect isopropanol, ethanol, and acetone at room temperature. Temperature-dependent
studies on acetone are carried out. A significant change in the current
levels is observed for different VOCs. A positive shift in the Dirac
point is noticed upon VOC exposure. The developed portable device
plays a vital role in analyzing sensors based on various active materials
for VOC detection.
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