Recently, there are great efforts that have been taken to suppressing/controlling the coffee ring effect, but it is of challenge to achieve inexpensive and efficient control with less disturbance, suitable for scalable production and highly enhancing the printing/dyeing color fastness. By only adding trace amounts of salt into the suspensions, here we experimentally achieve the facile and highly efficient control of the coffee ring effect of suspended matter on substrates of graphene, natural graphite, and polyethylene terephthalate surfaces. Notably, friction force measurements show that ion-controlled uniform patterns also greatly enhance color fastness. Molecular dynamics simulations reveal that, due to strong hydrated cation-π interactions between hydrated cations and aromatic rings in the substrate surface, the suspended matters are adsorbed on the surfaces mediated by cations so that the suspended matters are uniformly distributed. These findings will open new avenues for fabricating functional patterns on graphene substrates and will benefit practical applications including printing, coating, and dyeing.

Metals are widely used, from daily life to modern industry. Great efforts have been made to protect the metals with various coatings. However, the well-known conventional electrochemical corrosion induced by cations and the ubiquitous nature of the coffee-ring effect make these processes very difficult. Here, a scheme by two bridges of cations and ethylenediamine (EDA) is proposed to overcome the coffee-ring effect and electrochemical corrosion and experimentally achieve uniform, anticorrosive, and antiabrasive coatings on metallic surfaces. Anticorrosive capability reaches about 26 times higher than that without cation-controlled coatings at 12 h in extremely acidic, high-temperature, and high-humidity conditions and still enhances to 2.7 times over a week. Antiabrasive capability also reaches 2.5 times. Theoretical calculations show that the suspended materials are uniformly adsorbed on the surface mediated by complexed cations through strong cation–metal and cation−π interactions. Notably, the well-known conventional electrochemical corrosion induced by cations is avoided by EDA to control cations solubility in different coating processes. These findings provide a new efficient, cost-effective, facile, and scalable method to fabricate protective coatings on metallic materials and a methodology to study metallic nanostructures in solutions, benefitting practical applications including coatings, printing, dyeing, electrochemical protection, and biosensors.

Lithium extraction from brine or seawater using membrane technology has attracted extensive attention in recent years. Graphene oxide (GO), as one of the two-dimensional materials, has been proven as a competitive candidate for membranes. However, the GO membranes still suffer challenges for ion sieving due to the swelling in the aqueous solution. In this work, a GO–PEI membrane with positively charged channels was constructed by polyelectrolyte polyethyleneimine (PEI) molecular chain-grafted GO nanosheets. The GO–PEI membrane showed a high selectivity of 22.2 for Li+/Mg2+, together with a competitive Li+ permeation rate of 0.09 mol m–2 h–1 in a binary permeation test. In addition, the membrane showed excellent stability during the separation process. The enhanced Li+/Mg2+ separation performance of the GO–PEI membrane could be mainly attributed to the synergistic effect of size sieving and electrostatic repulsion. We further systematically studied the influence of various variables, such as PEI molecular weight, PEI content, membrane thickness, and ion concentration, on separation performance. This work deepens the understanding of membrane ion selectivity from multiple perspectives and puts forward a strategy to design a two-dimensional membrane structure from microscopic materials.

Great efforts have been made to separate micro/nanoparticles in small-volume specimens, but it is a challenge to achieve the simple, maneuverable and low-cost separation of sub-microliter suspension with large separation distances. By simply adding trace amounts of cations (Mg2+/Ca2+/Na+), we experimentally achieved the size-dependent spontaneous separation of colloidal particles in an evaporating droplet with a volume down to 0.2 μL. The separation distance was at a millimeter level, benefiting the subsequent processing of the specimen. Within only three separating cycles, the mass ratio between particles with diameters of 1.0 μm and 0.1 μm can be effectively increased to 13 times of its initial value. A theoretical analysis indicates that this spontaneous separation is attributed to the size-dependent adsorption between the colloidal particles and the aromatic substrate due to the strong hydrated cation-π interactions.