In real life applications, supercapacitors (SCs) often can only be used as part of a hybrid system together with other high energy storage devices due to their relatively lower energy density in comparison to other types of energy storage devices such as batteries and fuel cells. Increasing the energy density of SCs will have a huge impact on the development of future energy storage devices by broadening the area of application for SCs. Here, we report a simple and scalable way of preparing a three-dimensional (3D) sub-5 nm hydrous ruthenium oxide (RuO2) anchored graphene and CNT hybrid foam (RGM) architecture for high-performance supercapacitor electrodes. This RGM architecture demonstrates a novel graphene foam conformally covered with hybrid networks of RuO2 nanoparticles and anchored CNTs. SCs based on RGM show superior gravimetric and per-area capacitive performance (specific capacitance: 502.78 F g−1, areal capacitance: 1.11 F cm−2) which leads to an exceptionally high energy density of 39.28 Wh kg−1 and power density of 128.01 kW kg−1. The electrochemical stability, excellent capacitive performance, and the ease of preparation suggest this RGM system is promising for future energy storage applications.
Silver nanoplates with an extremely high aspect ratio (up to over 400) and a widely tunable surface plasmon resonance (SPR) band have been successfully synthesized by combining the concepts of selective ligand adhesion and seeded growth. Citrate ligands are used as the sole surfactant to effectively block overgrowth on the basal {111} facets and only allow growth in the lateral direction. By slowing down the reaction rate using Ag-citrate complex as precursor, the thin nature of Ag nanoplates is maintained with the edge length grown up to 4 μm, which ensures the high aspect ratio and the widely tunable SPR band. We also observe a size distribution focusing effect that helps to produce uniform nanoplates as well as narrow SPR bands over a wide range, which is important in many practical applications.
A simple solvothermal method has been discovered to synthesize single-walled flux-closure Ni-Co magnetic alloy nanorings in high yield, which are directly fabricated in a reaction solution and able to chronically exist in solution.
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