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Because of the diversification of industries in developing cities, the phenomenon of the simultaneous contamination of various kinds of pollutants is becoming common, and the environmental process of pollutants in multi-contaminated environmental mediums has attracted attention in recent years. In this study, p-arsanilic acid (ASA), a kind of organic arsenic feed additive that contains the arsenic group in a chemical structure, is used as a typical contaminant to investigate its adsorption on iron oxides and its implication for contaminated soils. The adsorption kinetics on all solids can be fitted to the pseudo-second-order kinetic model well. At the same mass dosage conditions, the adsorption amount per unit surface area on iron oxides follows the order α-FeOOH > γ-Fe2O3 > α-Fe2O3, which is significantly higher than that for actual soil, because of the lower content of iron oxides in actual soil. Lower pH conditions favor ASA adsorption, while higher pH conditions inhibit its adsorption as a result of the electrostatic repulsion and weakened hydrophobic interaction. The presence of phosphate also inhibits ASA adsorption because of the competitive effect. Correlations between the amount of ASA adsorption in actual soil and the Fe2O3 content, total phosphorus content, arsenic content, and organic matter content of actual soil are also investigated in this work, and a moderate positive correlation (R2 = 0.630), strong negative correlation (R2 = 0.734), insignificant positive correlation (R2 = 0.099), and no correlation (R2 = 0.006) are found, respectively. These findings would help evaluate the potential hazard of the usage of organic arsenic feed additives, as well as further the understanding of the geochemical processes of contaminants in complicated mediums.

The cost-benefit is a key factor when selecting an appropriate sponge city construction scheme. The research of applying intelligent technology to find cost-benefit efficient planning and construction of sponge city is urgently required. This paper established a multi-objective simulation optimization framework of sponge city construction which considered minimization of runoff control rate, pollutant control rate and life-cycle cost Non-dominated sorting genetic algorithm (NSGA-II) was successfully coupled to Storm water management model to complete the simulation-optimization process. A case study in Xining, China, was conducted to demonstrate the proposed framework. The results of this research suggested that 1) different sponge city construction schemes lead to different runoff control rates and pollutant control rates although under the same investment; 2) the runoff control rate and pollutant control rate total suspended solids decreased with the increase of the rainfall return period, while the cost of sponge city construction increased with the increase of rainfall return period. Furthermore, for T = 2-year, the sponge facility exhibited the most stable control effect on runoff and pollutants among the three different return periods (T = 2-year, 5-year, 10-year); 3) sponge city construction exhibited a “cost-benefit” efficient interval. For T = 2-year, the cost-benefit high efficiency interval of sponge city construction is calculated between 1.2 billion and 1.8 billion; for T = 5-year, the interval is between 1.2 billion and 1.8 billion, while for T = 10-year, the interval is between 1.3 billion and 2.1 billion. The above observations provide reference for reasonable and effective sponge city construction in Xining, China.