Furfural (FFR) was selectively hydrogenated in a single pot to tetrahydrofurfuryl alcohol (THFAL) over a Si–MFI molecular sieve supported Pd catalyst. Studies on catalyst screening revealed that both the metal function and the support were critical for directing the selectivity to the ring-hydrogenated product, THFAL. The structural feature of MFI as shown by XRD was completely retained in the used sample of the 3% Pd/MFI catalyst confirming its stability under reaction conditions. XRD, along with SEM characterization of the used samples, established retention of morphology of the structured silicate, suggesting a strong interaction between hexagonal porous silicate and Pd particles. The complete conversion of FFR with an enhanced selectivity of 95% to THFAL could be achieved by recycling the crude of the first hydrogenation experiment over the same 3% Pd/MFI catalyst.

Various noble metal catalysts were screened in a batch operation for a furfural (FFR) single-step decarbonylation and hydrogenation reaction to obtain THF in high selectivity. Among these, the 3% Pd/C showed complete FFR conversion with a total of 80% selectivity to ring hydrogenated products including tetrahydrofuran (THF). The order of activity exhibited by other noble metals was Pt/C > Re/C > Ru/C. Although Pt/C exhibited the highest activity, its decarbonylation and ring hydrogenation ability were the least (24%) with a major product selectivity of 66% to furfuryl alcohol (FAL). Similarly, the Cu catalyst gave almost complete selectivity to FAL. In a continuous operation (23 g catalyst bed), the 3% Pd/C catalyst showed higher selectivity of >40% compared to THF alone with complete FFR conversion and on-stream activity of ∼100 h. The reaction pathway elucidated from some control experiments revealed that the decarbonylation of FFR to furan over the Pd/C catalyst is a prerequisite for THF formation.

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Layer structured vanadium pentoxide (V2O5) microparticles were synthesized hydrothermally and successfully decorated by a facile wet chemical route, with ∼10–20 nm sized ruthenium nanoparticles.

Ammonia is widely needed in the chemical industry as well as in fertilizers for agriculture. However, in small as well as large quantities, it is not only hazardous for human health but also for our ecosystem. Therefore, ammonia sensing at low concentration with high sensitivity, selectivity and low response time as well as recovery time is important. Here, various nanosensors are fabricated using gold nanoparticles (∼15 nm), silica-gold nanoparticles coreshell particles and coreshell particles embedded in polypyrrol. Comparisons with bare polypyrrol and coreshell particles are also made. In fact, two types of coreshell particles with rod (∼300 nm×2 μm) shape and spheres (200 nm) of silica were used to anchor gold nanoparticles on them. A comparison showed that silica-gold core-shell particle with silica rods had the highest sensitivity (∼166% @ 130 ppm) amongst all. The sensor is simple to operate (only resistance change is measured), requires no heater as the sensing occurs at room temperature, and showed no response, except for ammonia, to other gases or humidity. It also has a low response time (4 s) and recovery time (10 s) at the lowest (10 ppm) ammonia concentration measured here. Thus, a simple, economical ammonia sensor has been demonstrated here.