Spherical and dense nickel hydroxide, Ni(OH) 2 , particles are produced by addition of ammonia or ammonium ions, NH 4 + , using a continuous precipitation. In this study, the nickel ion, Ni 2+ , concentrations and the NH 4 + concentrations in a suspended solution for the continuous precipitation of Ni(OH) 2 are examined, and the formation behaviors of spherical and dense Ni(OH) 2 particles are discussed by the relations between the Ni 2+ and NH 4 + concentrations. When NH 4 + was supplied into a suspended solution during the continuous precipitation of Ni(OH) 2 , Ni 2+ was present in a steady state and the Ni 2+ concentrations changed with the NH 4 + concentrations in a feed solution, with the solution pH and the residence times of suspended solutions in a crystallizer. The ratios of the NH 4 + concentrations to the Ni 2+ in a solution at steady state were different from the coordination number of NH 3 in a nickel ammine complex. Formation of Ni(OH) 2 precipitates when adding NH 4 + is discussed by the relations between the Ni 2+ and the NH 4 + concentrations in suspended solution for continuous and batch operations.is a type of cathode active material for a nickel−hydrogen secondary battery. Ni(OH) 2 precipitates are deposited by mixing of nickel sulfate, NiSO 4 , and sodium hydroxide, NaOH, aqueous solutions + → ↓+ NiSO 2NaOH Ni(OH) Na SO 4 2 2 4(1)The Ni(OH) 2 precipitates obtained by the reaction of a NiSO 4 aqueous solution with a NaOH solution are always amorphous and porous, resulting in lower apparent density. 1 On the contrary, when aqueous ammonia, NH 3 , is added into a suspension during a continuous precipitation, Ni(OH) 2 precipitates become spherical and dense. In this case, nickel ions, Ni 2+ , would bond with NH 3 and a nickel ammine complex would be formed. Then, nickel ammine complexes would be decomposed and Ni(OH) 2 precipitates would be formed by reaction with hydroxide ions, OH − , in a solution.Effects of operating conditions on the properties of products such as mean particle size, particle size distributions, PSDs, and apparent density are experimentally examined. When the amount of ammonium ion, NH 4 + , added into a suspended solution increased, mean particle size became larger, 2 PSDs became broader, 3 tapping density became higher, and nucleation rates of Ni(OH) 2 particles were reduced. 4 In addition, at high pH values both particle and crystallite sizes became smaller, 5,6 probably because of the enhancement of nucleation and deceleration of growth. 2 Moreover, it is reported that operating temperature and agitation speeds also influenced surface shapes and tapping densities of product particles. 3,4,6,7,8 Although changes in mean particle size and PSDs of Ni(OH) 2 with operating conditions for continuous precipitations were indicated, the Ni 2+ concentrations in suspended solutions are not pointed out. Moreover, when NH 4 + exists in an Ni(OH) 2 suspended solution the formation behaviors of Ni(OH) 2 precipitates are not revealed. The purposes of the present study are to clarify the...