Among the small cation sized rare earth sesquioxides, the reported transition pressure of cubic Tm2O3 is ambiguous. Pressure induced structural phase transition in cubic Tm2O3 has been reinvestigated using the synchrotron X-ray diffraction, Raman spectroscopy, and ab initio density functional theory (DFT) calculations up to a pressure of 25 GPa. Both the X-ray diffraction and Raman spectroscopic measurements revealed an irreversible polymorphic structural phase transition from type-C cubic to type-B monoclinic at around 12 GPa, whereas the same is predicted to be 8 GPa from the density functional theory. The phase transition observed at 12 GPa is in contrast to the literature and the reasoning has been established by other studies, viz., Raman spectroscopy and DFT. A third order Birch-Murnaghan equation of state fit to the experimental compressibility curve yielded a zero pressure bulk modulus of 149(2) GPa with the pressure derivatives 4.8(5) for the parent cubic phase and 169(2) GPa with the pressure derivative 4 for the high pressure monoclinic phase, respectively. These values are in good agreement with the calculated bulk modulus of 146 and 151 GPa for the cubic and monoclinic phases, respectively. Raman modes for the monoclinic phase of Tm2O3 are measured and reported for the first time. The mode Grüneisen parameter of different Raman modes for both cubic and monoclinic phases of Tm2O3 has also been determined. The experimental results are correlated with changes in the density of states near the Fermi level, which are indicative of structural instabilities in the parent cubic structure.

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Hybrid organic−inorganic 2-D perovskite bis-benzylammonium lead tetrachloride (BALC) is a room-temperature ferroelectric semiconductor. A structural phase transformation from the ambient Cmc2 1 structure is evident at 1.8 GPa from the Raman spectra, and this is confirmed by our high-pressure Xray diffraction studies that point to a centrosymmetric structure Cmcm at 1.7 GPa. The ambient phase is recoverable on decompression. Using density functional theory calculations, we have studied the intermolecular and intramolecular vibrations to get an idea of the structural changes as a function of pressure. The high-pressure transition is identified to be due to a distortion in the PbCl 6 octahedra and a conformation change in the molecule. There are several discontinuities, broadening, and splitting of the Raman bands, corresponding to NH 3 units above 1.8 GPa that point to rearrangements in the hydrogen bond network in the new phase. The ambient structure shows anisotropic compressibility, with a bulk modulus of 14.5 ± 0.33 GPa. As the new phase is a centrosymmetric structure, BALC is expected to lose its ferroelectricity above ∼1.8 GPa.