Precise control of structures and magnetic properties of a molecular material constitutes an important challenge to realize the tailor-made magnetic function. Herein, we reported that the ligand-directed coordination self-assembly of...

Based on a terpyridine derivative and two different dicarboxylate ligands, two new cobalt(II) coordination polymers, namely [Co(pytpy)(DClbdc)]n (1) and [Co(pytpy)(ndc)]n (2) (pytpy = 4'-(4-Pyridyl)-2,2':6',2''-terpyridine, H2DClbc = 2,5-Dichloroterephthalic acid, and H2ndc...

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Precise modulation of the structure and magnetic properties of coordination compounds is of great importance in the development of framework magnetic materials. Herein, we reported that the coordination self-assembly of...

A two-dimensional (2D) cobalt(II) metal−organic framework (MOF) constructed by a ditopic organic ligand, formulated as {[Co(Hbic)(H2O)]·4H2O}n (1) (H2bic = 1H-benzimidazole-5-carboxylic acid), was hydrothermally synthesized and structurally characterized. Single-crystal X-ray diffraction...