High-pressure minerals in meteorites are important records of shock events that have affected the surfaces of planets and asteroids. A widespread distribution of impact craters has been observed on the Vestan surface. However, very few high-pressure minerals have been discovered in Howardite-Eucrite-Diogenite (HED) meteorites. Here we present the first evidence of tissintite, vacancy-rich clinopyroxene, and super-silicic garnet in the eucrite Northwest Africa (NWA) 8003. Combined with coesite and stishovite, the presence of these high-pressure minerals and their chemical compositions reveal that solidification of melt veins in NWA 8003 began at a pressure of >~10 GPa and ceased when the pressure dropped to <~8.5 GPa. The shock temperature in the melt veins exceeded 1900 °C. Simulation results show that shock events that create impact craters of ~3 km in diameter (subject to a factor of 2 uncertainty) are associated with sufficiently high pressures to account for the occurrence of the high-pressure minerals observed in NWA 8003. This indicates that HED meteorites containing similar high-pressure minerals should be observed more frequently than previously thought.
Northwest Africa (NWA) 7755 is a newly found enriched lherzolitic shergottite. Here, we report its detailed petrography and mineralogy. NWA 7755 contains both poikilitic and non-poikilitic lithologies. Olivine has different compositional ranges in the poikilitic and non-poikilitic lithologies, Fa 30-39 and Fa 37-40 , respectively. Pyroxene in the non-poikilitic lithology is systematically Fe-richer than that in the poikilitic lithology. The chromite grains in non-poikilitic lithology are highly Ti-richer than those in the poikilitic lithology. The chemical variations of olivine, pyroxene, and chromite between the poikilitic and non-poikilitic lithologies support a two-stage formation model of lherzolitic shergottites. Besides planar fractures and strong mosaicism in olivine and pyroxene, shockinduced melt veins and pockets are observed in NWA 7755. Olivine grains within and adjacent to melt veins and/or pockets have either transformed to ringwoodite, amorphous phase, or dissociated to bridgmanite plus magnesiow€ ustite. Merrillite in melt veins has completely transformed to tuite; however, apatite only has partially transformed to tuite, indicating a relatively sluggish transformation rate. The partial transformation from apatite to tuite resulted in fractional devolatilization of Cl and F in apatite. The fine-grained mineral assemblage in melt veins consists mainly of bridgmanite, minor magnesiow€ ustite, Fe-sulfide, Fe-phosphide, and Ca-phosphate minerals. The coexistence of bridgmanite and magnesiow€ ustite in these veins indicates a shock pressure of >~24 GPa and a temperature of 1800-2000°C. Coesite and seifertite are probably present in NWA 7755. The presence of these high-pressure minerals indicates that NWA 7755 has experienced a more intense shock metamorphism than other enriched lherzolitic shergottites.
Records of space weathering are important for understanding the formation and evolution of surface regolith on airless celestial bodies. Current understanding of space weathering processes on asteroids including asteroid‐4 Vesta, the source of the howardite–eucrite–diogenite (HED) meteorites, lags behind what is known for the Moon. In this study, we studied agglutinates, a vesicular glass‐coating lithic clast, and a fine‐grained sulfide replacement texture in the polymict breccia Northwest Africa (NWA) 1109 with electron microscopy. In agglutinates, nanophase grains of FeNi and FeS were observed, whereas npFe0 was absent. We suggested that the agglutinates in NWA 1109 formed from fine‐grained surface materials of Vesta during meteorite/micrometeorite bombardment. The fine‐grained sulfide replacement texture (troilite + hedenbergite + silica) should be a result of reaction between S‐rich vapors and pyroxferroite. The unique Fe/Mn values of relict pyroxferroite indicate a different source from normal HED pyroxenes, arguing that the reaction took place on or near the surface of Vesta. The fine‐grained sulfide replacement texture could be a product of nontypical space weathering on airless celestial bodies. We should pay attention to this texture in future returned samples by asteroid exploration missions.
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