Field-tuning mechanisms of spin switching and spin reorientation (SR) transition were investigated in a series of highquality single crystal samples of Pr x Er 1−x FeO 3 (x = 0, 0.1, 0.3, 0.5) prepared using the optical floating zone method. The single crystal quality, structure, and axis orientation were determined by roomtemperature powder X-ray diffraction, back-reflection Laue X-ray diffraction, and Raman scattering at room temperature. Magnetic measurements indicate that the type and temperature region of SR transition are tuned by introducing different ratios of Pr 3+ doping (x = 0, 0.1, 0.3, 0.5). The trigger temperatures of spin switching and magnetization compensation temperature of Pr x Er 1−x FeO 3 crystals can be adjusted by doping with different proportions of Pr 3+ . Furthermore, the trigger temperature of the two types of spin switching in Pr 0.3 Er 0.7 FeO 3 along the a-axis can be regulated by an external field. Meanwhile, the isothermal magnetic field-triggered spin switching effect is also observed along the a and c-axes of Pr 0.3 Er 0.7 FeO 3 . An in-depth understanding of the magnetic coupling and competition between the R 3+ and Fe 3+ magnetic sublattices, within the RFeO 3 system, has important implications for advancing the practical applications of the relevant spin switching materials.
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