No abstract

As a relatively new source of processing energy, microwave energy offers many compelling advantages in materials processing over conventional heat sources. These advantages include greater flexibility, greater speed and energy savings, improved product quality and properties, and synthesis of new materials that cannot be produced by other heating methods. Studies of microwave processing of polymeric materials in the early 1960s led to a successful industrial application in the rubber industry. Since the mid-1980's, there has been a great deal of interest in microwave processing of polymeric materials worldwide. The discipline can be categorized in two major fields: microwave-assisted polymer physics (MAPP) and microwave assisted polymer chemistry (MAPC). This paper offers an overview of the state-of-the-art research on the field of MAPC, including polymer processing (curing of thermosets, processing of thermoplastics, and joining), polymer synthesis, plasma modification of polymer surfaces, plasma polymerization, polymer degradation, and production of nanomaterials. Most of these studies have focused on laboratory-scale, exploratory efforts. Challenges and possible future directions for the commercialization of microwave processing technologies are discussed.

The dielectric properties of a curing epoxy/amine system have been studied from 25 to 120°C at 2.45 GHz. The epoxy resins at different extents of curing exhibit a ␥ relaxation, which can be described by the Arrhenius rate law. The relaxation is attributed to the motions of the dipolar groups associated with the crosslinking system. A simple model is proposed to represent the temperature dependence of the dielectric properties. A complete description of the evolution of the parameters during the polymerization has been obtained. The nature of the information yielded by dielectrometry on the dynamics of the system is discussed.

Synchronization of coupled non-linear oscillators inspired by a central pattern generator (CPG) can control the bionic robot and promote the coordination and diversity of locomotion. However, for a robot with a strong mutual coupled structure, such neurobiological control is still missing. In this contribution, we present a σ-Hopf harmonic oscillator with decoupled parameters to expand the solution space of the locomotion of the robot. Unlike the synchronization of original Hopf oscillators, which has been fully discussed, the asymmetric factor of σ-Hopf oscillator causes a deformation in oscillation waveform. Using the non-linear synchronization theory, we construct the transition state model of the synchronization process to analyze the asymmetrical distortion, period change and duty ratio inconsistency. Then a variable coupling strength is introduced to eliminate the waveform deformation and maintain the fast convergence rate. Finally, the approach is used for the locomotion control of a bionic parallel waist of legged robot, which is a highly coupled system. The effectiveness of the approach in both independent and synthesis behavior of four typical motion patterns are validated. The result proves the importance of controllability of the oscillation waveform and the instantaneous state of the synchronization, which benefits the transition and transformation of the locomotion and makes the coupling motion more flexible.

The dielectric properties of a curing diglycidyl ether of bisphenol A (DGEBA)/Jeffamine D-230 system have been studied over the temperature range of 20 -90°C at 2.45 GHz. It was found that, generally, both the dielectric constant and the dielectric loss factor of the system increased with temperature and decreased as the reaction proceeded. The epoxy resins at different extents of cure exhibited the ␥ relaxation, which can be described by the Arrhenius Rate Law. The relaxation is attributed to the motions of the dipolar groups associated with the reactants. The Davidson-Cole model can represent the temperature dependencies of the dielectric properties. The nature of the information yielded by dielectrometry on the dynamics of the system is discussed. The evolution of the parameters of the models during the polymerization was mainly affected by the decreasing number of the dipolar groups involved in the reaction and increasing medium viscosity. POLYM. ENG. SCI., 45:1576 -1580, 2005.