Rational construction of heterostructures can compensate for the property shortfalls of a single component, which is a promising and challenging approach to develop high‐performance electrode materials. Herein, CuCo carbonate hydroxide nanowires@FeCo‐layered double hydroxide hexagonal nanosheets (CuCo‐CH@FeCo‐LDH) with a unique nanowire‐penetrated‐nanosheet architecture have been prepared through a facile two‐step hydrothermal method. The nanowires serve as fast channels for charge transfer of FeCo‐LDH and alleviate the blocked electroactive utilization induced by self‐stacking of LDH nanosheets, while the FeCo‐LDH contributes high specific capacitance. The resultant CuCo‐CH@FeCo‐LDH exhibits pseudocapacitive behavior with near‐rectangular CV profiles and overall enhanced electrochemical performance compared to individual CuCo‐CH and FeCo‐LDH. An assembled asymmetric supercapacitor (CuCo‐CH@FeCo‐LDH//N/S co‐doped graphene) delivers high energy density (46.9 Wh kg−1 at 750 W kg−1), high power density (29.0 Wh kg−1 at 7500 W kg−1), and outstanding cycling stability (81.7 % capacitance retention after 5000 cycles).

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