It is still a challenge for flexible electronic materials to realize integrated strain sensors with a large linear working range, high sensitivity, good response durability, good skin affinity and good air permeability. In this paper, we present a simple and scalable porous piezoresistive/capacitive dual-mode sensor with a porous structure in polydimethylsiloxane (PDMS) and with multi-walled carbon nanotubes (MWCNTs) embedded on its internal surface to form a three-dimensional spherical-shell-structured conductive network. Thanks to the unique spherical-shell conductive network of MWCNTs and the uniform elastic deformation of the cross-linked PDMS porous structure under compression, our sensor offers a dual piezoresistive/capacitive strain-sensing capability, a wide pressure response range (1–520 kPa), a very large linear response region (95%), excellent response stability and durability (98% of initial performance after 1000 compression cycles). Multi-walled carbon nanotubes were coated on the surface of refined sugar particles by continuous agitation. Ultrasonic PDMS solidified with crystals was attached to the multi-walled carbon nanotubes. After the crystals were dissolved, the multi-walled carbon nanotubes were attached to the porous surface of the PDMS, forming a three-dimensional spherical-shell-structure network. The porosity of the porous PDMS was 53.9%. The large linear induction range was mainly related to the good conductive network of the MWCNTs in the porous structure of the crosslinked PDMS and the elasticity of the material, which ensured the uniform deformation of the porous structure under compression. The porous conductive polymer flexible sensor prepared by us can be assembled into a wearable sensor with good human motion detection ability. For example, human movement can be detected by responding to stress in the joints of the fingers, elbows, knees, plantar, etc., during movement. Finally, our sensors can also be used for simple gesture and sign language recognition, as well as speech recognition by monitoring facial muscle activity. This can play a role in improving communication and the transfer of information between people, especially in facilitating the lives of people with disabilities.

Microfluidics has recently received more and more attention in applications such as biomedical, chemical and medicine. With the development of microelectronics technology as well as material science in recent years, microfluidic devices have made great progress. Porous structures as a discontinuous medium in which the special flow phenomena of fluids lead to their potential and special applications in microfluidics offer a unique way to develop completely new microfluidic chips. In this article, we firstly introduce the fabrication methods for porous structures of different materials. Then, the physical effects of microfluid flow in porous media and their related physical models are discussed. Finally, the state-of-the-art porous microfluidic chips and their applications in biomedicine are summarized, and we present the current problems and future directions in this field.