Singlet oxygen ( 1 O 2 ) plays important roles in many biological processes. However, it is very difficult to detect 1 O 2 in the intracellular environment because of its relatively low concentration and short lifetime. Here, we developed a ratiometric probe based on semiconducting polymer dots (Pdots) that can sensitively detect 1 O 2 in live cells. An organic dye, singlet oxygen sensor green (SOSG), was doped in polyfluorene Pdots, and excitation energy was efficiently transferred from the polymer to the SOSG dye. Accordingly, the Pdots showed constant blue fluorescence as a reference, and increased green fluorescence upon singlet oxygen generation. The ratiometric response of Pdots was examined in the intracellular environment by in situ 1 O 2 generation with a photosensitizer and light irradiation. Both spectroscopic measurements and confocal imaging were performed to monitor intracellular 1 O 2 generation during photodynamic therapy using the Pdot probe. Our results indicate that the SOSG-doped Pdots are promising for intracellular 1 O 2 detection.
In this paper, we propose two kinds of translation type chaotic systems for creating 2 N + 1-and 2(N + 1)-scrolls chaotic attractors from a simple three-dimensional system, which are named the translation-2 chaotic system (aa < 0) and the translation-3 chaotic system (aa > 0). We also propose the successful design criterion for constructing 2 N + 1-and 2(N + 1)-scrolls, respectively. Then, the dynamics property of the translation-2 chaotic system is studied in detail. MATLAB simulation results show that very sophisticated dynamical behaviors and unique chaotic behaviors of the system. Finally, the definition and criterion of multi-scroll attractors for the translation-3 chaotic system is obtained. Three representative examples are shown in some classical chaotic systems that can be equally obtained via the set parameters of the translation type chaotic system. Furthermore, we show that the translation type chaotic systems have similar but topologically non-equivalent chaotic attractors, and they are the three-dimensional ordinary differential equations.
We propose a systematic methodology for creating 2N + 1-scroll chaotic attractors from a simple three-dimensional system, which is named as the translation chaotic system. It satisfies the condition a12a21 = 0, while the Chua system satisfies a12a21 > 0. In this paper, we also propose a successful (an effective) design and an analytical approach for constructing 2N + 1-scrolls, the translation transformation principle. Also, the dynamics properties of the system are studied in detail. MATLAB simulation results show very sophisticated dynamical behaviors and unique chaotic behaviors of the system. It provides a new approach for 2N + 1-scroll attractors. Finally, to explore the potential use in technological applications, a novel block circuit diagram is also designed for the hardware implementation of 1-, 3-, 5-, and 7-scroll attractors via switching the switches. Translation chaotic system has the merit of convenience and high sensitivity to initial values, emerging potentials in future engineering chaos design.
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