With the exhaustion of coal resources in shallow coal seams, many mining areas have moved to deep mining, and the coal storage environment is obviously affected by the mining depth, mainly manifested as the increase of gas pressure and temperature, which makes the adsorption characteristics of deep coal seam gas much more complicated than shallow coal seam. Based on this, this paper chooses Pingdingshan coking coal as the research object, using Hsorb-2600 high-temperature and high-pressure gas adsorption instrument to carry on isothermal adsorption experiment. According to the adsorption theory and the uniqueness of the adsorption characteristics cure, the adsorption model was analyzed and studied. The results show that the predicted curve of coal seam gas adsorption isotherm is in good agreement with the measured curve, the relative error is less than 10%, and the adsorption characteristic curve is logarithmic. At the same time, the model is used to study the variation of adsorbed gas amount with mining depth. The results show that the adsorbed gas amount increases first and then decreases with coal burial depth.
The incidence of Müllerian duct anomalies in women is rare, associating with urinary tract anomalies such as horseshoe or pelvic kidney, renal agenesis, duplication of the collecting system, or ectopic uterus. Septate uterus is one type of congenital uterine anomalies, in which there is a septum from the fundus to the cervix. Currently, it is believed that hysteroscopic metroplasty is a leading choice for patients if their recurrent spontaneous abortion is resulted from septate uterus. But, some people refuse to have a surgery, and successfully delivery. In this case report, we report a successful pregnancy with two gestational sacs, one in each half-cavity, in a woman with septate uterus after transfer of three embryos into one half–cavity. Finally, the women gave birth to two healthy babies in our hospital.
To study the effect of high temperature and high pressure on the adsorption characteristics of coking coal, Liulin coking coal and Pingdingshan coking coal were selected as the research objects, and isotherm adsorption curves at different temperatures and pressures were obtained by combining isotherm adsorption experiments and molecular dynamics methods. The effect of high temperature and high pressure on the adsorption characteristics of coking coal was analyzed, and an isothermal adsorption model suitable for hightemperature and high-pressure conditions was studied. The results show that the adsorption characteristics of deep coking coal can be well characterized by the molecular dynamics method. Under a supercritical condition, the excess adsorption capacity of methane decreases with the increase of temperature. With the increase of pressure, the excess adsorption capacity rapidly increases in the early stage, temporarily stabilizes in the middle stage, and decreases in the later stage. Based on the classical adsorption model, the adsorption capacity of coking coal under high-temperature and high-pressure environments is fitted. The fitting degree ranges from good to poor. The order is D−R > D−A > L−F >BET > Langmuir, and combined with temperature gradient, pressure gradient, and the D−R adsorption model, it can be seen that after 800 m deep in Liulin Mine and 400 m deep in Pingdingshan Mine, the adsorption capacity of coking coal to methane decreases with the increase of depth.
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