To halt the pandemic of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), governments around the world have imposed policies, such as lockdowns, mandatory mask wearing, and social distancing. The application of disinfecting materials in shared public facilities can be an additional measure to control the spread of the virus. Copper is a prominent material with antibacterial and antiviral effects. In this study, we synthesized copper nanoparticles (CuNPs) as a surface coating agent and assessed their antiviral activity against SARS-CoV-2. CuNPs with a mean size of 254 nm in diameter were synthesized from copper sulfate as a source and were predominantly composed of copper oxide. The synthesized CuNPs were mixed with resin-based paint (CuNP/paint) and sprayed on the surface of stainless steel remnants. SARS-CoV-2 lost 97.8% infectivity on the CuNP/paint-coated surface after 30 min of exposure and more than 99.995% infectivity after 1 h of exposure. The inactivation rate was approximately 36-fold faster than that on the paint alone-coated and uncoated surfaces. The CuNP/paint-coated surface showed powerful inactivation of SARS-CoV-2 infectivity, although further study is needed to elucidate the inactivation mechanisms. Applications of CuNP/paint coatings to public or hospital facilities and other commonly touched areas are expected to be beneficial.
Purpose – The purpose of this paper is to evaluate the mechanical properties of photopolymer/CB (carbon black) nanocomposite when applied in a visible-light rapid prototyping (RP) machine. Design/methodology/approach – The mechanical properties of the samples such as hardness and tensile strength along with thermal stability were analyzed. The curing time behavior of the photopolymer/CB nanocomposites was tested by using a rigid-body pendulum rheometer. The shrinkage property and dimensional stability were also analyzed using the technique according to ASTM D2566 and ASTM D1204, respectively. Findings – The results showed that the prototype fabricated from pristine photopolymer tended to exhibit poor mechanical properties and low thermal stability. However, after adding the photopolymer with various concentrations of nano-CB and dispersant in appropriate composition, the photopolymer/CB nanocomposite prototype not only reduced its curing time but also enhanced its mechanical properties, thermal stability and dimensional stability. Practical implications – The presented results can be used in a visible-light RP machine. Originality/value – The mechanical and thermal properties of photopolymer are improved with nano-CB additives for a RP system.
Influence of weathering effect in natural environment on thermal properties hybrid kenaf blast/glass fibre and unsaturated polyester composite M Mohammed, A R Rozyanty, B O Beta et al. (10, 20, 30, 40,and 80 wt.%) using mechanical blending method. The blends were cured at room temperature using methyl ethyl ketone peroxide (MEKP) (4 wt.%) as catalyst initiator without the presence of catalystaccelerator. The effect of vinyl ester composition on theenhancement of mechanical and thermal properties of unsaturated polyester/vinyl ester blends was investigated.The polymer blends were characterized by Fourier Transform Infra Red (FTIR)spectroscopy, tensile testing, hardness testing, scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). IR spectra showed UP and VE peaks. The curing copolymerization reactionoccurred at vinyl (C=C) bonds. The addition of vinyl esters enhanced mechanical and thermal properties. The UP/VE blends showed homogeneous morphology, transparent and copolymer thermoset blend.Keywords: unsaturated polyester, vinyl ester, polymer blend, thermal properties IntroductionUnsaturated polyester is a widely used thermosetting resin. Unsaturated polyester has a reactive vinyl (carbon-carbon double) bond. Styrene is added to unsaturated polyester as asolvent and acrosslinking agent for curing reaction. The organic peroxide is used to initiatethe reaction. Organic salt isadded to accelerate the reaction. The polymer is achieved as a result of random condensation copolymerization reaction between styrene and unsaturated vinyl double bonds by free radical mechanismforming crosslinked network structure [1,2]. Unsaturated polyester is a resin (prepolymer) with low price, light weight, easy processing and water resistance. Unsaturated polyester commonly used in laminating resin, composites, coating, adhesive, microelectronic, aerospace, building, automotive, and shipbuilding. However, unsaturated polyester shows limited mechanical and thermal properties. It is necessary to enhance the properties of unsaturated polyester.The properties of unsaturated polyester have been enhanced by theadditionof carbon fiber , fly ash, carbon nanotube, and polyamide [3][4][5][6]. Vinyl ester is an attractivehigh-performance thermoset polymer. Vinylester has reactive double bonds with rigid epoxy structure. Vinyl ester is synthesized by the reaction of epoxy with methacrylic
Kenaf (Hibiscus cannabinus L.) was a plant belonging to the Malvaceae family. Kenaf was a natural fiber that has attracted researchers to explore its properties as reinforcement materials in composites. In addition, calcium carbonate (CC) particle can also improve the mechanical properties of composite. The aim of this study was to describe the fabrication of calcium carbonate particle reinforced kenaf/polyester hybrid composite. The hybrid composites were prepared using hand lay-up process with different particle loading (2.5%, 5%, 7.5%, 10% and 20% by weight). The hybrid composites were tested for tensile strenght using ASTM D368 standard. The highest tensile strength were showed for 5% wt calcium carbonate reinforced kenaf/polyester hybrid composite in this investigation. It was also observed that the density for hybrid composite decreased as the particle content increased.
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