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The present article is dedicated to the adsorption of CO on reduced 2% Pd/Al 2 O 3 and 2% Pd-x% Sn/Al 2 O 3 (weight %, x = 2 or 5 wt %) in the 300−713 K temperature range to study the geometric and electronic effects of Sn on the palladium adsorption sites. Using Fourier transform infrared (FTIR) spectroscopy, it is shown that the insertion of Sn leads to (a) the total disappearance of the Pd sites forming bridged CO species (denoted as "B"), which are the dominant species on Pd 0 particles and (b) a significant increase in the Pd sites forming linear CO species (denoted as "L"). This is ascribed to a geometric effect of Sn that dilutes the superficial palladium sites. The measurement of the individual heats of adsorption of the different adsorbed CO species by using two original temperature-programmed adsorption equilibrium methods (denoted AEIR and TPAE) allows the estimation of the electronic effect of Sn on the Pd sites. On 2% Pd/ Al 2 O 3 , in parallel to the formation of two strongly adsorbed B CO species, two linear L1 Pd 0 and L2 Pd 0 CO species are formed, which exhibit different heats of adsorption. For the dominant L1 Pd 0 CO species, the heat of adsorption decreases linearly, from 92 kJ/mol to 54 kJ/mol, as its coverage increases at coverage 0 and 1, respectively, while that of the L2 Pd 0 species is >165 kJ/mol at coverage 1. On the two Pd−Sn containing particles, two linear CO species are formed denoted L1 2Pd−xSn and L2 2Pd−xSn with x = 2 or 5. The L1 2Pd−xSn species dominates the CO adsorption on the two solids. It is shown that its heat of adsorption (which is slightly dependent on x) linearly varies with its coverage: ∼90 kJ/mol and ∼50 kJ/mol at low and high coverage, respectively. The comparison with the heat of adsorption of L1 Pd 0 indicates that the electronic effect of tin is very modest, compared to its geometric effect. This conclusion is consistent with literature data dedicated to DFT calculation. Moreover, (a) XRD and TEM/ EDX analysis suggest that bimetallic particles such as Pd 3 Sn and Pd 2 Sn are present and (b) the impact of tin on the H 2 chemisorption on Pd 0 sites are presented.

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When CO 2þ /ZSM5 catalysts are prepared by solid state exchange between H-ZSM5 and cobalt acetate, CO 2þ ions form layered cobalt phyllosilicate at the surface of the zeolite grains, bringing about a reassessment of the chemistry involved in the preparation of catalytic systems by solid state exchange.

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