[1] New thermal-petrologic models of subduction zones are used to test the hypothesis that intermediate-depth intraslab earthquakes are linked to metamorphic dehydration reactions in the subducting oceanic crust and mantle. We show that there is a correlation between the patterns of intermediate-depth seismicity and the locations of predicted hydrous minerals: Earthquakes occur in subducting slabs where dehydration is expected, and they are absent from parts of slabs predicted to be anhydrous. We propose that a subducting oceanic plate can consist of four petrologically and seismically distinct layers: (1) hydrated, fine-grained basaltic upper crust dehydrating under equilibrium conditions and producing earthquakes facilitated by dehydration embrittlement; (2) coarse-grained, locally hydrated gabbroic lower crust that produces some earthquakes during dehydration but transforms chiefly aseismically to eclogite at depths beyond equilibrium; (3) locally hydrated uppermost mantle dehydrating under equilibrium conditions and producing earthquakes; and (4) anhydrous mantle lithosphere transforming sluggishly and aseismically to denser minerals. Fluid generated through dehydration reactions can move via at least three distinct flow paths: percolation through local, transient, reaction-generated high-permeability zones; flow through mode I cracks produced by the local stress state; and postseismic flow through fault zones.

[1] We present a new compilation of physical properties of minerals relevant to subduction zones and new phase diagrams for mid-ocean ridge basalt, lherzolite, depleted lherzolite, harzburgite, and serpentinite. We use these data to calculate H 2 O content, density and seismic wave speeds of subduction zone rocks. These calculations provide a new basis for evaluating the subduction factory, including (1) the presence of hydrous phases and the distribution of H 2 O within a subduction zone; (2) the densification of the subducting slab and resultant effects on measured gravity and slab shape; and (3) the variations in seismic wave speeds resulting from thermal and metamorphic processes at depth. In considering specific examples, we find that for ocean basins worldwide the lower oceanic crust is partially hydrated (<1.3 wt % H 2 O), and the uppermost mantle ranges from unhydrated to $20% serpentinized ($2.4 wt % H 2 O). Anhydrous eclogite cannot be distinguished from harzburgite on the basis of wave speeds, but its $6% greater density may render it detectable through gravity measurements. Subducted hydrous crust in cold slabs can persist to several gigapascals at seismic velocities that are several percent slower than the surrounding mantle. Seismic velocities and V P /V S ratios indicate that mantle wedges locally reach 60-80% hydration.

Water and hydrous minerals play a key part in geodynamic processes at subduction zones by weakening the plate boundary, aiding slip and permitting subduction-and indeed plate tectonics-to occur. The seismological signature of water within the forearc mantle wedge is evident in anomalies with low seismic shear velocity marking serpentinization. However, seismological observations bearing on the presence of water within the subducting plate itself are less well documented. Here we use converted teleseismic waves to obtain observations of anomalously high Poisson's ratios within the subducted oceanic crust from the Cascadia continental margin to its intersection with forearc mantle. On the basis of pressure, temperature and compositional considerations, the elevated Poisson's ratios indicate that water is pervasively present in fluid form at pore pressures near lithostatic values. Combined with observations of a strong negative velocity contrast at the top of the oceanic crust, our results imply that the megathrust is a low-permeability boundary. The transition from a low- to high-permeability plate interface downdip into the mantle wedge is explained by hydrofracturing of the seal by volume changes across the interface caused by the onset of crustal eclogitization and mantle serpentinization. These results may have important implications for our understanding of seismogenesis, subduction zone structure and the mechanism of episodic tremor and slip.

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Warm and cool subduction zones exhibit differences in seismicity, seismic structure, and arc magmatism, which reflect differences in metamorphic reactions occurring in subducting oceanic crust. In southwest Japan, arc volcanism is sparse and intraslab earthquakes extend to 65 kilometers depth; in northeast Japan, arc volcanism is more common and intraslab earthquakes reach 200 kilometers depth. Thermal-petrologic models predict that oceanic crust subducting beneath southwest Japan is 300 degrees to 500 degrees C warmer than beneath northeast Japan, resulting in shallower eclogite transformation and slab dehydration reactions, and possible slab melting.