Rivers may receive pharmaceuticals, personal care products, and environment estrogens, which are emerging concerns, from various sources. Understanding the fate of these emerging contaminants (ECs) from the sources to their receiving river is important for assessing their ecosystem risk. Here, the occurrence, seasonal variation, spatial distribution, and ecological risk of 22 ECs in water and sediments from the Jilin Songhua River, as well as in the effluents from the riverside Jilin wastewater treatment plant (WWTP) were investigated. Results indicated that estriol with the highest median concentration of 21.5 ng L in the river water and with the highest median concentration of 481.5 ng g in the sediments, and methylparaben with the highest concentration of 29.6 ± 2.9 ng L in the WWTP effluents were the predominant contaminants. The total concentration of ECs in the river water in the dry season was about 1.5 times higher than that in the wet season. The concentrations of these ECs close to the contaminated tributary and the WWTP were relatively high. Risk assessment showed that the maximum risk quotient value of estrone was 1.07 in the river water and estriol was 2.10 in the effluents. In addition, erythromycin posed generally medium risk in the river water and WWTP effluents. It should be paid attention to the prior control of the three contaminants in the river region.

The occurrence, spatial distribution, seasonal variation, sources, and ecological risks of polycyclic aromatic hydrocarbons (PAHs) in overlying water and surface sediments from Tiaozi River, which is an urban river running through the downtown of Siping City, a traditional industrial city of northeastern China, were investigated. The total PAH concentrations (ΣPAHs) in water varied from 473.5 to 2674.3 ng/L with a mean value of 1272.6 ng/L and ranged from 601.5 to 2906.3 ng/g with a mean value of 1534.4 ng/g in sediments. Both the individual and total PAH concentrations in water and sediments decreased from upstream to downstream, and the average ΣPAHs between the four seasons in water and sediments decreased in the following order of winter> autumn> spring> summer. The composition of the PAHs was characterized by an abundance of PAHs from 2 rings to 4 rings, and the predominant components were naphthalene, chrysene, and benzo(a)anthracene. The identification of the source indicated that coal combustion could be the main contributor to the PAHs. The equivalent toxic concentrations of benzo[a]pyrene in the water ranged from 11.5 to 33.1 ng/L, which were much higher than the concentration limit, suggesting that PAHs in the water could cause potential risks. The risk assessment of PAHs in sediments also showed that PAHs could cause negative effects on aquatic organisms in this river.

Understanding the ecosystem risk of contaminants in the surface water of lakes in scenic areas is important for environmental management. Here, a comprehensive ecological risk assessment evaluation method was established to assess the ecological risk of 14 water quality indicators of Baiyangdian Lake in the spring, summer, and autumn. The results show that the indices of ammonia nitrogen and permanganate exceed the Class III standard limit for water quality. Baiyangdian Lake is generally in a state of mesotrophication, and some areas are slightly eutrophic; the degree of eutrophication is higher in the summer and autumn than in the spring. The lake water at the inlet is eutrophic and polluted, with an inferior water quality. Heavy metals are almost not detected in Baiyangdian Lake. The heavy metal pollution indices of Nanliuzhuang and Caiputai are slightly higher than those of other areas. The ecological risk quotient of petroleum is high. The comprehensive ecological risk of the Baiyangdian Lake is at Level 4, owing to the continuous development of aquaculture and tourism in recent years. We should start the monitoring, management, and strengthening of water quality supervision to achieve the ecological and environmental planning goals of Baiyangdian Lake.