No abstract

In the context of energy conservation and the reduction of CO2 emissions, inconsistencies between the inevitable emission of CO2 in traditional hydrogen production methods and eco-friendly targets have become more apparent over time. The catalytic decomposition of methane (CDM) is a novel technology capable of producing hydrogen without releasing CO2. Since hydrogen produced via CDM is neither blue nor green, the term “turquoise” is selected to describe this technology. Notably, the by-products of methane cracking are simply carbon deposits with different structures, which can offset the cost of hydrogen production cost should they be harvested. However, the encapsulation of catalysts by such carbon deposits reduces the contact area between said catalysts and methane throughout the CDM process, thereby rendering the continuous production of hydrogen impossible. This paper mainly covers the CDM reaction mechanisms of the three common metal-based catalysts (Ni, Co, Fe) from experimental and modelling approaches. The by-products of carbon modality and the key parameters that affect the carbon formation mechanisms are also discussed.

No abstract

No abstract

The blending of hydrogen gas into natural gas pipelines is an effective way of achieving the goal of carbon neutrality. Due to the large differences in the calorific values of natural gas from different sources, the calorific value of natural gas after mixing with hydrogen may not meet the quality requirements of natural gas, and the quality of natural gas entering long-distance natural gas and urban gas pipelines also has different requirements. Therefore, it is necessary to study the effect of multiple gas sources and different pipe network types on the differences in the calorific values of natural gas following hydrogen admixing. In this regard, this study aimed to determine the quality requirements and proportions of hydrogen-mixed gas in natural gas pipelines at home and abroad, and systematically determined the quality requirements for natural gas entering both long-distance natural gas and urban gas pipelines in combination with national standards. Taking the real calorific values of the gas supply cycle of seven atmospheric sources as an example, the calorific and Wobbe Index values for different hydrogen admixture ratios in a one-year cycle were calculated. The results showed that under the requirement of natural gas interchangeability, there were great differences in the proportions of natural gas mixed with hydrogen from different gas sources. When determining the proportion of hydrogen mixed with natural gas, both the factors of different gas sources and the factors of the gas supply cycle should be considered.