HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L'archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d'enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.

No abstract

No abstract

Self-assembled organic-inorganic [C 6 H 14 N]PbI 3 crystals were synthesized. The crystal structure consists of one-dimensional semiconductor chains formed by infinite PbI 6 face-sharing octahedra aligned along the a-axis. The organic cations are linked to the inorganic chains by N-H· · ·I hydrogen bonds and act as insulator barriers. The vibrational properties of [C 6 H 14 N]PbI 3 were studied using polarized Raman scattering and infrared (IR) absorption. The observed Raman and IR spectral features were identified by comparison with the vibrational properties of homologous compounds and with the vibrational wavenumbers calculated using the ab initio PM3 method. Moreover, the photoluminescence and diffuse reflectance of [C 6 H 14 N]PbI 3 single crystals, along with the UV-Vis absorption of spin-coated films, were measured. A strong green-blue luminescence due to radiative recombinations of 1D excitons is observed. The Stokes shift is estimated at 70 meV.

No abstract