The novel core–shell type polymeric supports with accessible phosphorus groups were synthesised in the search for new reactive materials designed for the synthesis of functional resins. Amberlite XAD-4 adsorbent was impregnated with tri octyl phosphine oxides (Cyanex 921), which were then polymerized in the polymer carrier structure. The syntheses were evaluated by capturing FT-IR spectra, SEM micrographs, and analysing the sorption process. Batch studies were conducted to study the influence of some factors like pH, contact time, the metal ions concentration, and temperature on sorption efficiency of La (III) ions. The results showed that the optimum conditions were at pH equal to 0.5 and an equilibrium contact time of 30 min. According to the results of the sorption data analysis, the pseudo-second-order and Langmuir models were better fitted than the other estimated models. The sorption capacity of La (III) ions into impregnated resin as adsorbent martial was 54.25 mg g−1. The results revealed that the used adsorbent has been used successfully as a promising material for the elimination and recovery of La ions from the aqueous solutions. The impregnated resin exhibits a high chemical stability, reusability and fast equilibration. Further, the above procedure has been successfully employed for the application of real sample.
The activated carbon (AC) was modified by molecules of quinoline (Q) and the new prepared AC impregnated by Q was characterized using Fourier transform infrared (FTIR), Raman spectroscopy, surface measurements, scanning electron microscope (SEM) and transmission electron microscope (TEM). These analytical techniques demonstrated a successful preparation of AC-Q as a new material which was examined for its sorption behavior for natural uranium. The sorption results by batch mode indicated the optimum conditions for 94.5% removal of U(VI) ions at pH 4.7 and an equilibrium contact time of 90 min. The analysis of sorption data revealed that the pseudo-second-order and Langmuir were more fitted than other estimated models. The sorption capacity of U(VI) was ∼63 mg/g onto AC-Q as adsorbent martial. The thermodynamic data demonstrated that the sorption of uranium is endothermic and spontaneous. New mechanism was supposed based on the role of the abrasive material quinoline on the mechanical removal of uranium from aqueous solution.
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