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PIV and LIF techniques were conducted to reveal relationship between sedimentation and mass exchange property in a groyne field. It was found from the PIV measurements that different bed-form conditions, that is to say, with and without bed slope, yielded corresponding gyre formations. The other experiment, the LIF results allowed us reasonably to evaluate transfer velocity of dye through boundary between mainstream and dead water zone, They suggest that mass exchange properties have significant relations with horizontal gyres, thereby, with the conditions of bed slope. The results normalized by turbulence intensity and length scale of gyre were in good agreement with a large-eddy model.