Acid corrosion may cause the deterioration of the fire resistance of the intumescent fire retardant coatings, especially for the coatings used in the acid polluted environment. This paper reported the results of an experimental study of degradation in fire protection performance of intumescent coating for steel elements after different times of immersion in the hydrochloric acid solution. After acid erosion, the thickness of the coating thinned, the surface became rough and had cracks and broken holes. The size of the pores in the char layer was larger and uneven, and some 'cement' parts were formed in the char layer. The TG/DTG results showed in the low temperature stage the curve was relatively flat. In the medium temperature stage, the number of the weight loss troughs decreased; the shape of the troughs simplified; and the top weight loss rate increased. In the high temperature stage, the troughs near 593 °C flattened gradually, and the top weight loss rate became smaller, while the top weight loss rate became larger around 674 °C. And there were significant changes in the thermal dynamic parameters. A prediction method of remained fire resistance property for the acid erosion coatings was proposed, by comprehensively considering the physical and chemical characteristics change trends of the corroded coating. And this method can be a reference for the fire safety evaluation of the built protected steel structure.
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